28131-24-0

Basic information

• Product Name: Carbamic acid, methylphenyl-, 1,1-dimethylethyl ester
• CAS NO: 28131-24-0
• Molecular Formula: C12H17NO2
• Molecular Weight: 207.272
• Mol File: 28131-24-0.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: Carbamic acid, methylphenyl-, 1,1-dimethylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, methylphenyl-, 1,1-dimethylethyl ester(28131-24-0)
• EPA Substance Registry System: Carbamic acid, methylphenyl-, 1,1-dimethylethyl ester(28131-24-0)

Safety Data

• Hazardous Substances Data: 28131-24-0(Hazardous Substances Data)

Upstream product

• 496-15-1 1-indoline 
• 24424-99-5 di-tert-butyl dicarbonate 
• 24424-95-1 di-tert-butyl tricarbonate 
• 110-05-4 di-tert-butyl peroxide 
• 103-71-9 phenyl isocyanate 
• 62-53-3 aniline 
• 599-62-2 N-methyl-N-phenyltoluenesulfonamide 
• 100-61-8 N-methylaniline 
• 792909-19-4 2,3-dihydroindole-1-carboxylic acid phenyl ester 
• 792909-18-3 2,3-dihydroindole-1-carboxylic acid allyl ester 
• 132431-12-0 N-(benzyloxycarbonyl)indoline 
• 61589-17-1 1-Ethoxycarbonyl-2,3-dihydro-1H-indole 
• 250296-58-3 N-tert-Butoxycarbonyl-N-trifluoromethylsulfonyl-4-trifluoromethylanilide 
• 3422-01-3 tert-butyl phenylcarbamate 

Downstream Products

• 1738-99-4 N-(3-phenylpropyl)aniline 
• 56165-31-2 N-(2-phenylpropyl)aniline 
• 1227053-82-8 β-methyl-N-phenylbenzene ethanamine 
• 1739-14-6 N-(3-(p-tolyl)propyl)aniline 
• 1227053-85-1 N-(2-(2,4-dimethylphenyl)propyl)aniline 
• 1227053-90-8 N-(3-(2,4-dimethylphenyl)propyl)aniline 
• 1227053-83-9 N-(2-(4-tert-butylphenyl)propyl)aniline 
• 1227053-88-4 N-(3-(4-(tert-butyl)phenyl)propyl)aniline 
• 1739-13-5 N-phenyl-3-(4-methoxyphenyl)propane-1-amine 
• 244016-01-1 trans-N-phenyl-5-phenyl-4-penten-1-amine 
• 579-10-2 N-acetyl-N-methylaniline 
• 1438886-44-2 N-(3-(4-(trifluoromethyl)phenyl)propyl)aniline 

Relevant articles and documents

Photochemical regioselective C(sp3)-H amination of amides using N-haloimides

A metal-free regioselective C(sp3)-H amination of amides using N-haloimides in the presence of lithium tert-butoxide and visible light is presented herein. This photoexcited approach is straightforward, and it aminates a wide variety of amides under mild conditions without the use of photocatalysts, external radical initiators, or oxidants. A halogen-bonded intermediate between the tert-butoxide base and the N-haloimide is proposed to be responsible for the increased photoreactivity. Calculations show that the formation of this electron donor-acceptor complex presents an exergonic energy profile.

Nickel-catalyzed C-O bond reduction of aryl and benzyl 2-pyridyl ethers

The reduction of aryl and benzyl 2-pyridyl ethers with sodium isopropoxide was carried out via nickel-catalyzed C-OPy bond cleavage, giving reductive products in reasonable to excellent yields. This method allowed the 2-pyridyloxy group to be directly rem

Efficient N-Boc protection of amines by a reusable heterogeneous solid acid nanocatalyst at room temperature

An efficient and rapid protocol for chemoselective N-Boc protection of various structurally different aryl, aliphatic, and heterocyclic amines is reported with (Boc)2O using mesoporous silica phenylsulfonic acid (SBA-15-Ph-SO3H) as a recyclable and heterogeneous solid acid nanocatalyst under solvent-free condition at ambient temperature. The catalyst can be easily recovered and reused for ten reaction cycles for protection of amines without considerable loss of activity. The advantages of this green method are simplicity, easy workup, chemoselectivity, short reaction time, and excellent yield.