152389-45-2Relevant academic research and scientific papers
Enantiomerically Pure Dimethyl (2S)-N-(9-Phenylfluoren-9-yl)-3,4-didehydroglutamate as Chiral Educt. Chirospecific Synthesis of (+)-5-O-Carbamoylpolyoxamic Acid and 3-Alkylglutamates
Paz, Manuel M.,Sardina, F. Javier
, p. 6990 - 6995 (1993)
We report here a short and efficient synthesis (four steps, 78percent overall yield) of dimethyl (2S)-N-(9-phenylfluoren-9-yl)-3,4-didehydroglutamate (1) in enantiomerically pure form from L-glutamic acid.The C-C double bond in 1 was introduced by selecti
