152419-59-5

Basic information

• Product Name: Methyl-3-(benzyloxy) butanoate
• CAS NO: 152419-59-5
• Molecular Weight: 222.241
• Mol File: 152419-59-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Methyl-3-(benzyloxy) butanoate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl-3-(benzyloxy) butanoate(152419-59-5)
• EPA Substance Registry System: Methyl-3-(benzyloxy) butanoate(152419-59-5)

Safety Data

• Hazardous Substances Data: 152419-59-5(Hazardous Substances Data)

Upstream product

• 72315-95-8 methyl 3-methyl-4-oxo-4-phenylbutanoate 
• 1487-49-6 3-hydroxybutyric acid methyl ester 
• 98-88-4 benzoyl chloride 
• 1201813-85-5 methyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-propanoate 
• 623-43-8 methyl crotonate 

Relevant articles and documents

When Chirality Meets “Buchwald-Type” Phosphines: Synthesis and Evaluation in Frustrated Lewis Pair-, Lewis Base- and Palladium-Promoted Asymmetric Catalysis

We describe the synthesis of axially chiral “Buchwald ligand”-like biphenylphosphines in highly enantioenriched form. These monodentate phosphines, biphenyl analogues of Hayashi's MOP ligands, were evaluated in phosphine-promoted organocatalysis and in hydrosilylations catalyzed by palladium or by frustrated Lewis pairs. As expected, the title phosphines appeared best suited for transition metal catalysis where they provided higher asymmetric induction.