152480-63-2Relevant academic research and scientific papers
Condensation of 9-fluorenone and phenol using an ionic liquid and a mercapto compound synergistic catalyst
Lei, Yan,Yu, Limei,Shen, Maochang,Luo, Shikang,Gao, Zhanxian
supporting information, p. 15700 - 15705 (2019/10/19)
A series of ionic liquids (ILs) were synthesized and their Hammett acidities (H0) were determined using 4-nitroaniline as the indicator. The relationship among IL's structure, the acid strength, and the catalytic performance in the condensation reaction of 9-fluorenone with phenol was discussed. The effective H0 range of ionic liquids that can catalyse the condensation reaction was obtained. Moreover, the catalysis of the mercapto compound co-catalyst was also systematically studied. According to the analysis of how the structure of the sulfydryl co-catalyst affects the percent conversion of 9-fluorenone and the selectivity of BHPF, a mechanism for the reaction in the IL-thiol cooperative catalytic system was proposed. The present work gave a clear clue to design novel IL catalysts for the synthesis of BHPF.
