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15263-53-3

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15263-53-3 Usage

Chemical Properties

solid

Uses

Cartap is obtained by hydrolyzing 1,1-dithiocyanato- 2-dimethylaminopropane with hydrochloric acid. Cartap is the pro-insecticide of the natural toxin nereistoxin. It is used for the control of chewing and sucking insects, at almost all stages of development, on many crops. Its structure is based on that of the naturally occurring neurotoxin, nereistoxin.

Metabolism

Cartap is hydrolyzed in base to the dihydronereistoxin, which is oxidized to the insecticide, nereistoxin (32). The conversion occurs within plants, and the monoxide (33)was identified as aminor metabolite. In rats, cartap was rapidly excreted in urine. It was hydrolyzed, converted to the sulfoxide, and N-demethylated (9).

Toxicity evaluation

Nereistoxin does not inhibit cholinesterase. Instead, it acts as an antagonist at the nicotinic acetylcholine receptor and blocks neural transmission (10).

Check Digit Verification of cas no

The CAS Registry Mumber 15263-53-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,5,2,6 and 3 respectively; the second part has 2 digits, 5 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 15263-53:
(7*1)+(6*5)+(5*2)+(4*6)+(3*3)+(2*5)+(1*3)=93
93 % 10 = 3
So 15263-53-3 is a valid CAS Registry Number.
InChI:InChI=1/C7H15N3O2S2/c1-10(2)5(3-13-6(8)11)4-14-7(9)12/h5H,3-4H2,1-2H3,(H2,8,11)(H2,9,12)

15263-53-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name cartap

1.2 Other means of identification

Product number -
Other names t-1258

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:15263-53-3 SDS

15263-53-3Synthetic route

1-(N,N-dimethylamino)-2,3-dichloropropane
5443-48-1

1-(N,N-dimethylamino)-2,3-dichloropropane

potassium thiocarbamate

potassium thiocarbamate

cartap
15263-53-3

cartap

Conditions
ConditionsYield
With tetrabutylammomium bromide In N,N-dimethyl-formamide at 20 - 80℃; for 7h;
1-(N,N-dimethylamino)-2,3-dichloropropane
5443-48-1

1-(N,N-dimethylamino)-2,3-dichloropropane

sodium thiocarbamate

sodium thiocarbamate

cartap
15263-53-3

cartap

Conditions
ConditionsYield
With tetrabutylammomium bromide In water at 20℃; for 11h; Temperature; Reflux;
cartap
15263-53-3

cartap

Cu(2+)-calcein blue complex

Cu(2+)-calcein blue complex

A

Calcein blue
54375-47-2

Calcein blue

B

Cu(2+)-cartap complex

Cu(2+)-cartap complex

Conditions
ConditionsYield
In aq. buffer for 0.133333h; pH=8;
cartap
15263-53-3

cartap

1,3-Bis(carbamoylthio)-2-(N,N-dimethylamino)-propane hydrochloride
15263-52-2

1,3-Bis(carbamoylthio)-2-(N,N-dimethylamino)-propane hydrochloride

Conditions
ConditionsYield
With hydrogenchloride In methanol at 0 - 10℃; for 0.5h; Solvent;

15263-53-3Related news

Highly sensitive and selective Cartap (cas 15263-53-3) nanosensor based on luminescence resonance energy transfer between NaYF4:Yb,Ho nanocrystals and gold nanoparticles08/05/2019

Fluorescent detection is an attractive method for the detection of toxic chemicals. However, most chemosensors that are currently utilized in fluorescent detection are based on organic dyes or quantum dots, which suffer from instability, high background noise and interference from organic impuri...detailed

Developmental toxicity of Cartap (cas 15263-53-3) on zebrafish embryos08/04/2019

Cartap is a widely used insecticide which belongs to a member of nereistoxin derivatives and acts on nicotinic acetylcholine receptor site. Its effects on aquatic species are of grave concern. To explore the potential developmental toxicity of cartap, zebrafish embryos were continually exposed, ...detailed

Highly sensitive and selective colorimetric detection of Cartap (cas 15263-53-3) residue in agricultural products08/03/2019

The residue of pesticide has posed a serious threat to human health. Fast, broad-spectrum detection methods are necessary for on-site screening of various types of pesticides. With citrate-coated Au nanoparticles (Au NPs) as colorimetric probes, a visual and spectrophotometric method for rapid a...detailed

Simultaneous determination of Cartap (cas 15263-53-3) and its metabolite in tea using hydrophilic interaction chromatography tandem mass spectrometry and the combination of dispersive solid phase extraction and solid phase extraction08/02/2019

Risk assessment of cartap residue in tea should include the exposure of cartap and its metabolite due to rapid degradation of cartap into nereistoxin. Herein, a reliable method for determination of cartap and nereistoxin in tea was developed by hydrophilic interaction chromatography tandem mass ...detailed

15263-53-3Relevant articles and documents

Synthesis method of cartap

-

Paragraph 0029-0041, (2017/07/21)

The invention provides a synthesis method of cartap, and relates to a synthesis method of 1,3-bis(carbamyl sulfonium)-2-(N,N-dimethylamino) propane hydrochloride. An original medicine of cartap is prepared from carbon oxysulfide, ammonia and 1-(N,N-dimethylamino)-2,3-propylene dichloride (chloride for short) through a one-pot method in an alkaline solution. By the adoption of the one-pot method for reaction step by step to prepare the cartap, the synthesis method has the advantages of low equipment investment, low energy consumption, easiness and convenience for operation and substantial improvement of the conversion rate. According to the synthesis method, the use of organic raw materials such as sodium thiosulfate (sodium thiosulfate) and sodium cyanide is avoided, so that generation of a large amount of sewage containing sodium sulfite and sodium cyanide is avoided. The synthesis method substantially increases the selectivity and the conversion rate in a reaction process, thus improving the production efficiency and greatly reducing the production cost.

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