1527-14-6

Basic information

• Product Name: 2-Phenylthiobenzenemethanol
• Synonyms: 2-(Phenylthio)benzyl alcohol;2-Phenylthiobenzenemethanol;o-(Phenylthio)benzyl alcohol
• CAS NO: 1527-14-6
• Molecular Formula: C₁₃H₁₂OS
• Molecular Weight: 216
• Mol File: 1527-14-6.mol
• Article Data: 13

Chemical Properties

• Melting Point: 44 °C(Solv: ethyl ether (60-29-7); ligroine (8032-32-4))
• Boiling Point: 348℃
• Flash Point: 170℃
• Appearance: /
• Density: 1.21
• PKA: 14.09±0.10(Predicted)
• CAS DataBase Reference: 2-Phenylthiobenzenemethanol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Phenylthiobenzenemethanol(1527-14-6)
• EPA Substance Registry System: 2-Phenylthiobenzenemethanol(1527-14-6)

Safety Data

• Hazardous Substances Data: 1527-14-6(Hazardous Substances Data)

Upstream product

• 89-98-5 2-chloro-benzaldehyde 
• 108-98-5 thiophenol 
• 88-67-5 2-Iodobenzoic acid 
• 100-51-6 benzyl alcohol 
• 446-52-6 2-Fluorobenzaldehyde 
• 36943-39-2 2-(phenylthio)benzaldehyde 
• 5159-41-1 2-iodobenzyl alcohol 
• 1527-12-4 2-(phenylthio)benzoic acid 
• 882-33-7 diphenyldisulfane 
• 120454-38-8 bis<2-(thiophenoxy)benzyl> oxalate 
• 1527-13-5 2-Phenylthiobenzoesaeureethylester 

Downstream Products

• 1527-17-9 2-[2-(phenylsulfanyl)phenyl]acetic acid 
• 1527-16-8 2-phenylthiophenylacetonitrile 
• 37660-43-8 2-(phenylthio)benzyl bromide 
• 1527-15-7 2-(phenylthio)benzyl chloride 
• 261-31-4 thioxanthene 
• 36943-39-2 2-(phenylthio)benzaldehyde 
• 120454-38-8 bis<2-(thiophenoxy)benzyl> oxalate 

Relevant articles and documents

Environmentally Friendly and Recyclable CuCl 2-Mediated C-S Bond Coupling Strategy Using DMEDA as Ligand, Base, and Solvent

Simple reaction conditions and recyclable reagents are crucial for environmentally friendly industrial applications. An environment-friendly, recyclable and economic strategy was developed to synthesize diaryl chalcogenides by the CuCl2-catalyzed C S bondformation reaction via iodobenzenes and benzenethiols/1,2-diphenyldisulfanes using N,N'-dimethylethane-1,2-diamine (DMEDA) as ligand, base, and solvent. For these reactions, especially the reactions of diiodobenzenes and aminobenzenethiols/disulfanediyldianilines, a range of substrates are compatible and give the corresponding products in good to excellent yields. Both of the reagents in the catalytic system (CuCl2/DMEDA) are inexpensive, conveniently separable, and recyclable for more than five cycles.

COMPOUND AND COMPOSITION CONTAINING THE SAME, AND METHOD FOR MANUFACTURING DEVICE USING THE COMPOSITION

PROBLEM TO BE SOLVED: To provide a compound which efficiently absorbs extreme ultraviolet radiation (EUV) such as KrF excimer laser and ArF excimer laser or an electron beam, has low sensitivity to OoB, and has high contrast. SOLUTION: A compound is represented by formula (1) and formula (2). In formulae (1) and (2), R1a and R1a are each independently a first monovalent organic group containing a divalent hydrocarbon group selected from an alkylene group; a group bonded directly to sulfur atom (S+) is the divalent hydrocarbon group; R2 is a hydrogen atom, an alkyl group and the like; R3 to R6 are a hydrogen atom, a hydroxy group or a second monovalent organic group; X- is a monovalent anion; and R1a and R1b in Formula (1) or R1a and R1b in Formula (2) may be bonded to each other to form a ring. SELECTED DRAWING: None COPYRIGHT: (C)2017,JPOandINPIT

An efficient copper-catalyzed cross-coupling reaction of thiols with aryl iodides

Commercially available Cu2O powder is a very reactive catalyst for the coupling of thiols to aryl iodides. A variety of functional groups including esters, unprotected amines, alcohols, and heterocycles tolerate the reaction conditions. Moreover, di-ortho-substituted aryl iodides with sterically demanding substrates were also coupled to give the desired aryl thioethers in good to excellent yields. Copyright