15280-53-2

Basic information

• Product Name: GADOLINIUM ACETATE
• Synonyms: GADOLINIUM ACETATE;GADOLINIUM ACETATE HYDRATE;GADOLINIUM ACETATE TETRAHYDRATE;GADOLINIUM (III) ACETATE HYDRATE;GADOLINIUM(III) ACETATE TETRAHYDRATE;Gadolinium (III) acetate tetrahydrate (99.9% Gd) (REO);GadoliniumacetatetetrahydrateREOwhitextl;GADOLINIUM(III) ACETATE TETRAHYDRATE 99.9%-GD)
• CAS NO: 15280-53-2
• Molecular Formula: 3C₂H₃O₂*Gd*4H₂O
• Molecular Weight: 406.44
• Product Categories: metal acetate salt
• Mol File: 15280-53-2.mol
• Article Data: 1

Chemical Properties

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: white/crystal
• Density: 1,611 g/cm3
• Water Solubility: 11.6g/100mL H2O (25°C) [CRC10]
• CAS DataBase Reference: GADOLINIUM ACETATE(CAS DataBase Reference)
• NIST Chemistry Reference: GADOLINIUM ACETATE(15280-53-2)
• EPA Substance Registry System: GADOLINIUM ACETATE(15280-53-2)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36
• TSCA: No
• Hazardous Substances Data: 15280-53-2(Hazardous Substances Data)

Usage

Chemical Properties

tricl white crystal(s) [STR93] [CRC10]

InChI:InChI=1/C2H4O2.Gd.4H2O/c1-2(3)4;;;;;/h1H3,(H,3,4);;4*1H2/q;+3;;;;/p-1

Upstream product

• 64-19-7 acetic acid 

Downstream Products

• 1335421-91-4 (5,10,15,20-tetraphenylporphyrinato)acetatogadolinium(III) 

Relevant articles and documents

Chemistry of rare earth hypocoordinate oxocluster cations: Formation of novel oxoacetate clusters

A fast atom bombardment mass spectrometry (FAB MS) study of Ln(CH3COO)3·4H2O(Ln=Gd (1), Y (2)) was undertaken to explore the chemistry of hypocoordinate rare earth oxide cations (e.g. [LnO]+ and [Ln3O4]+), which are frequently encountered in FAB MS of rare earth compounds. A series of novel rare earth oxoacetate clusters, [LnxOy,(CH3COO)3x-(2y+1)] + (3) was readily and preferentially obtained over oxide clusters. Oxygenation is important for the stability of large clusters, i.e. 3, x≥4. Molecules or molecular ions such as [LnO]+,Ln2O3 and [Ln3O4]+ are coordinatively unsaturated, and may have a more extensive coordination chemistry.