15286-12-1Relevant academic research and scientific papers
A palladium-catalyzed oxidative cross-coupling reaction between aryl pinacol boronates and H-phosphonates in ethanol
Chen, Te-Hsuan,Reddy, Daggula Mallikarjuna,Lee, Chin-Fa
, p. 30214 - 30220 (2017)
The first successful oxidative coupling reaction of aryl pinacol boronic esters with H-phosphonates to deliver aryl phosphorous compounds is reported herein. These reactions between aryl boronic reagents and H-phosphonates were carried out synergistically using a Pd catalyst, additive and oxidant. Without using bases and ligands, phosphorylation was accomplished in an environmentally-friendly manner under mild conditions in ethanol.
C-P bond formation of cyclophanyl-, and aryl halides: Via a UV-induced photo Arbuzov reaction: A versatile portal to phosphonate-grafted scaffolds
Br?se, Stefan,Hassan, Zahid,Nieger, Martin,O?wald, Simon,Zippel, Christoph
, p. 3309 - 3312 (2022/02/11)
A new versatile method for the C-P bond formation of (hetero)aryl halides with trimethyl phosphite via a UV-induced photo-Arbuzov reaction, accessing diverse phosphonate-grafted arenes, heteroarenes and co-facially stacked cyclophanes under mild reaction
Photoinduced Transition-Metal-Free Cross-Coupling of Aryl Halides with H-Phosphonates
Zeng, Huiying,Dou, Qian,Li, Chao-Jun
supporting information, p. 1301 - 1305 (2019/02/19)
Photoinduced transition-metal- and photosensitizer-free cross-coupling of aryl halides (including Ar-Cl, Ar-Br, and Ar-I) with H-phosphonates (including dialkyl phosphonates and diarylphosphine oxides) is reported. Various functional groups were tolerated, including ester, methoxy, dimethoxy, alkyl, phenyl, trifluoromethyl, and heterocyclic compounds. This simple and green strategy provides a practical pathway to synthesize arylphosphine oxides.
A mild electroassisted synthesis of (hetero)arylphosphonates
Sengmany, Stéphane,Ollivier, Anthony,Le Gall, Erwan,Léonel, Eric
supporting information, p. 4495 - 4500 (2018/06/29)
The electrochemically-assisted synthesis of (hetero)arylphosphonates from (hetero)aryl halides and dimethyl phosphite is described. Very mild and simple conditions are employed as the cross-coupling is carried out in galvanostatic mode, in an undivided ce
