152873-62-6

Basic information

• Product Name: 4(1H)-Pyridinone, 2,3-dihydro-2-phenyl-1-(phenylmethyl)-
• CAS NO: 152873-62-6
• Molecular Formula: C18H17NO
• Molecular Weight: 263.339
• Mol File: 152873-62-6.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: 4(1H)-Pyridinone, 2,3-dihydro-2-phenyl-1-(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 4(1H)-Pyridinone, 2,3-dihydro-2-phenyl-1-(phenylmethyl)-(152873-62-6)
• EPA Substance Registry System: 4(1H)-Pyridinone, 2,3-dihydro-2-phenyl-1-(phenylmethyl)-(152873-62-6)

Safety Data

• Hazardous Substances Data: 152873-62-6(Hazardous Substances Data)

Upstream product

• 54125-02-9 danishefsky's diene 
• 780-25-6 N-benzylidene benzylamine 
• 174841-04-4 1-(2-Iodo-benzyl)-2-phenyl-2,3-dihydro-1H-pyridin-4-one 
• 27845-50-7 (E)-N-benzylidenebenzylamine 
• 1423-60-5 methyl ethynyl ketone 
• 100-52-7 benzaldehyde 
• 100-46-9 benzylamine 

Downstream Products

• 167705-56-8 N-benzyl-2-phenyl-4-piperidinone 
• 1335247-94-3 N-benzyl-2-phenyl-5-(4'-(trifluoromethyl)phenyl)-2,3-dihydropyridin-4(1H)-one 
• 1335247-95-4 N-benzyl-5-(4'-bromophenyl)-2-phenyl-2,3-dihydropyridin-4(1H)-one 
• 1017601-71-6 N-benzyl-5-(4'-methoxyphenyl)-2-phenyl-2,3-dihydropyridin-4(1H)-one 
• 1049677-48-6 N-benzyl-5-(4'-chlorophenyl)-2-phenyl-2,3-dihydropyridin-4(1H)-one 
• 1335247-93-2 N-benzyl-2-phenyl-5-(4'-tolyl)-2,3-dihydropyridin-4(1H)-one 
• 1335247-92-1 N-benzyl-2,5-diphenyl-2,3-dihydropyridin-4(1H)-one 
• 1335247-96-5 N-benzyl-5-(1'-naphthyl)-2-phenyl-2,3-dihydropyridin-4(1H)-one 

Relevant articles and documents

Synthesis, structure and catalytic activity of an air-stable titanium triflate, supported by an amine tris(phenolate) ligand

An air- and moisture-stable titanium(IV) triflate, 3, supported by a C3-symmetric amine tris(phenolate) ligand has been synthesised, characterised by X-ray crystallography and demonstrated to be an excellent catalyst for formal aza-Diels-Alder reactions.

Regio- and stereoselective intramolecular Heck reactions of N-acyl-2,3-dihydro-4-pyridones

Intramolecular Heck reactions of N-acyl-2,3-dihydro-4-pyridones provide polycyclic heterocycles with high regio- and stereoselectivity.

Scandium(III)-zeolites as new heterogeneous catalysts for imino-diels-alder reactions

This study demonstrates the first zeolite-catalyzed synthesis of piperidine derivatives, including peptidomimetics and indoloquinolizidine alkaloids. The approach developed utilizes a highly effective one-pot reaction cascade, through imine formation and

Rapid synthesis of carbohydrate derivatives, including mimetics of C-linked disaccharides and C-linked aza disaccharides, using the hetero-Diels-Alder reaction

In this work we demonstrate the value of performing a hetero-Diels-Alder reaction (HDAR) between Danishefsky's diene and a range of aldehydes or imines, under microwave irradiation. By using a range of aldehydes and imines, including those derived from carbohydrates, access to functionalized 2,3-dihydro-4H- pyran-4-ones or 2,3-dihydro-4-pyridinones in good to excellent synthetic yields is possible. A particular strength of the methodology is its ability to access mimetics of C-linked disaccharides and C-linked aza disaccharides, targets of current therapeutic interest, in a rapid, convenient, and diastereoselective manner. The effect of high pressure on the HDARs involving carbohydrate-derived aldehydes and imines is also explored, with enhancement in yields occurring for the aldehyde substrates. Finally, HDARs using carbohydrate derived ketones, enones, and enals are described under a range of conditions. Optimum results were obtained under high-pressure conditions, with highly functionalized carbohydrate derivatives being afforded, in good yields, in this way.