15294-84-5

Basic information

• Product Name: Benzenesulfonamide, 4-methyl-N-(4-morpholinylmethylene)-
• CAS NO: 15294-84-5
• Molecular Formula: C12H16N2O3S
• Molecular Weight: 268.337
• Mol File: 15294-84-5.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: Benzenesulfonamide, 4-methyl-N-(4-morpholinylmethylene)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, 4-methyl-N-(4-morpholinylmethylene)-(15294-84-5)
• EPA Substance Registry System: Benzenesulfonamide, 4-methyl-N-(4-morpholinylmethylene)-(15294-84-5)

Safety Data

• Hazardous Substances Data: 15294-84-5(Hazardous Substances Data)

Upstream product

• 110-91-8 morpholine 
• 941-55-9 4-toluenesulfonyl azide 
• 75-07-0 acetaldehyde 
• 5807-04-5 3-morpholinoacrylaldehyde 
• 92050-44-7 methyl β-morpholinomethacrylate 
• 1423-60-5 methyl ethynyl ketone 
• 98-59-9 p-toluenesulfonyl chloride 
• 623-47-2 propynoic acid ethyl ester 
• 51759-38-7 4-{4-[2-(4-chloro-phenyl)-2H-tetrazol-5-yl]-buta-1,3-dienyl}-morpholine 
• 92972-00-4 1-(p-bromophenylthiazolyl-2)-4-morpholinobutadiene 
• 536-74-3 phenylacetylene 
• 13831-03-3 tert-butyl prop-2-ynoate 
• 109-02-4 4-methyl-morpholine 
• 70-55-3 toluene-4-sulfonamide 

Downstream Products

• 1192-58-1 N-methylpyrrole aldehyde 

Relevant articles and documents

Copper-Catalyzed Coupling of Sulfonamides with Alkylamines: Synthesis of (E)-N-Sulfonylformamidines

Herein, we describe an efficient copper-catalyzed coupling of sulfonamides with alkylamines to synthesize (E)-N-sulfonylformamidines. The reaction is accomplished under mild conditions without the use of a corrosive acid or base as an additive. It tolerat

Synthesis of Aryl- and Hetarylpyrazoles

Hetaryldieneamines (1) react with sulfonyl azides to give 3-hetarylpyrazoles (5).Similarly, N,N-dimethyl-4-phenyldieneamine-2-carboxylic acid methyl ester (6) affords 3-phenylpyrazole-5-carboxylic acid methyl ester (7). - Keywords: Cycloaddition; Dieneami

Catalyst-free one-pot, four-component approach for the synthesis of di- And tri-substituted: N -sulfonyl formamidines

A straightforward one-pot, multicomponent approach was developed to synthesize di- and tri-substituted N-sulfonyl formamidines from sulfonyl chlorides, NaN3, ethyl propiolate, and primary/secondary amines under mild conditions without catalysts or additives. Structural analysis of the di-substituted sulfonyl formamidines indicated formation of the E-syn/anti isomeric form. Tri-substituted analogues only formed E-isomers.

Electrochemically generatedN-iodoaminium species as key intermediates for selective methyl sulphonylimination of tertiary amines

Reported herein is a straightforward protocol for approachingN-sulphonylamidinesviaan electricity-driven, iodine-mediated cross dehydrogenative condensation (CDC) between sulphonamides and tertiary amines, which features exclusive N-CH3selectivity for the amine partners. Mechanistic studies indicate that anin situgeneratedN-iodoaminium species serves as the key intermediate.