15313-94-7

Upstream product

• 622-95-7 4-chlorobenzyl bromide 
• 106-43-4 para-chlorotoluene 
• 73377-44-3 N-(p-Chlorobenzyl)-2,4,6-triphenylpyridinium nitrate 
• 76950-79-3 1-(4-Chloro-benzyl)-2-methylsulfanyl-4,6-diphenyl-pyridinium; iodide 
• 76950-86-2 1-(4-Chloro-benzyl)-4,6-diphenyl-1H-pyridine-2-thione 
• 104-86-9 4-chlorobenzylamine 
• 35424-56-7 1-chloro-4-(iodomethyl)benzene 

Downstream Products

• 104-88-1 4-chlorobenzaldehyde 

Relevant academic research and scientific papers

Thermal decomposition of N-acyloxy-N-alkoxyamides a new HERON reaction

The HERON reaction has been observed in the thermal decompositions of N-acyloxy-N-alkoxyamides 1b, members of the class of anomeric amides. The N,N-bisoxo-substitution results in reduced amide resonance and this, combined with an nO-σ*NOAcyl anomeric destabilization of the N-OAcyl bond, results in their intramolecular rearrangement to anhydrides 42 and alkoxynitrenes 43 in competition with homolysis of the N-OAcyl bond to alkoxyamidyls 51. The primary HERON product alkoxynitrenes are scavenged by oxygen, giving a nitrate ester, in competition with a rearrangement to nitriles and dimerization to hyponitrites, leading, under the conditions, to alcohols and aldehydes. Persistent alkoxyamidyls most likely form a 1,3-diradical in a solvent-cage reaction, which cyclizes to 3,5-disubstituted-(5H)-1,4,2-dioxazoles 47. Substituent effects support this competition reaction. CSIRO 2010.

Establishment of heterolytic and homolytic Y-NO2 bond dissociation energy scales of nitro-containing compounds in acetonitrile: Chemical origin of NO2 release and capture

(Chemical Equation Presented) The first heterolytic and homolytic N(O)-NO2 bond dissociation energy scales of three types Y-nitro (Y = N, O) compounds and corresponding radical anions in acetonitrile were established by using titration calorimetry combined with relevant electrochemical data through proper thermodynamic cycles.

Anionic Surfactants Catalysis in the Two-phase Oxidation of Toluene Derivatives with Cerium Ammonium Nitrate. A Facile Synthesis of Some Benzaldehydes

The catalytic activity of sodium 1-dodecanesulfonate, sodium dodecyl sulfate, disodium 2-dodecyl-1,3-propanediyl disulfate (1) and trisodium 2,2-bis(sulfonatemethyl)tetradecylsulfate(2) was tested in the two-phase oxidation of p-xylene with cerium ammonium nitrate (CAN).Also various tolouene derivatives were oxidized with CAN in the presence of sodium dodecyl sulfate.The observed reaction enhancements are discussed in terms of the micelle-substrate interaction.The catalytic oxidation of some toluene derivatives (3) with a subsequent thermal rearrangement of the oxida tion product offers a simple synthetic route to benzaldehydes 4.

THE ROLE OF NITRATE FREE RADICALS IN THE PHOTOCHEMICAL SIDE-CHAIN NITROOXYLATION OF ALKYLBENZENES BY CERIUM(IV) AMMONIUM NITRATE IN ACETONITRILE

It is suggested that the reactive species in the CAN-induced photochemical side-chain nitrooxylation of alkylbenzenes is the nitrate radical, which probably acts as one-electron oxidant.

Mercury-assisted solvolyses of alkyl halides. Simple procedures for the preparation of nitrate esters, acetate esters, alcohols and ethers

The reactions of a wide variety of alkyl halides with mercury(I) and/or (II) nitrate in 1,2-dimethoxyethane, mercury(II) acetate in acetic acid, aqueous mercury(II) perchlorate, and mercury(II) perchlorate in alcohol solvents have been investigated; as a result, simple high yield procedures for the conversion of alkyl halides into the corresponding nitrate esters, acetate esters, alcohols and ethers have been developed.