15315-30-7Relevant academic research and scientific papers
Reaction of tri- and tetrasubstituted alkenes with the low-temperature oxidizing system aluminum terf-butylate-terf-butyl hydroperoxide
Martynova,Stepovik,Dodonov
, p. 736 - 741 (2007/10/03)
The system consisting of aluminum tert-butylate and tert-butyl hydroperoxide under mild conditions (20°C) oxidizes tri- and tetrasubstituted ethylenes containing at least one α-methyl group. The reaction proceeds via formation of tertiary allylic hydroperoxides and their subsequent transformations into unsaturated alcohols and epoxy alcohols, and also into carbonyl compounds. The presence of the latter products suggests degradation of the carbon skeleton of alkenes.
DIRECT LIQUID-PHASE OXIDATION OF 3-METHYLBUT-1-ENE BY ATMOSPHERIC OXYGEN
Akhmed'Yanova, R. A.,Litvintsev, I. Yu.,Liakumovich, A. G.
, p. 357 - 364 (2007/10/02)
An examination has been made of different variants of the direct oxidation of 3-methylbut-1-ene by atmospheric oxygen in the liquid phase.The most promising of the variants examined for the oxidation of this α-isoamylene is direct oxidation in the presence of a bimetallic catalytic system.Target products were isolated from the oxidate - 3-metyhylbut-1-ene oxide and dimethylvinylcarbinol of sufficient purity.
