Hydroperoxide, 1,1-dimethyl-2-propenyl

Base Information

• Chemical Name: Hydroperoxide, 1,1-dimethyl-2-propenyl
• CAS No.: 15315-30-7
• Molecular Formula: C5H10O2
• Molecular Weight: 102.133
• DSSTox Substance ID: DTXSID20472700
• Nikkaji Number: J843.063B
• Wikidata: Q82301773
• Mol file: 15315-30-7.mol

Synonyms:15315-30-7;Hydroperoxide, 1,1-dimethyl-2-propenyl;2-methyl-3-buten-2-yl hydroperoxide;SCHEMBL374799;DTXSID20472700;DACKWPCRUFMCRC-UHFFFAOYSA-N

Chemical Property of Hydroperoxide, 1,1-dimethyl-2-propenyl

Chemical Property:

• XLogP3: 0.8
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 102.068079557
• Heavy Atom Count: 7
• Complexity: 66.5

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C=C)OO

Technology Process of Hydroperoxide, 1,1-dimethyl-2-propenyl

There total 2 articles about Hydroperoxide, 1,1-dimethyl-2-propenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-methyl-but-2-ene (513-35-9) → 2-(oxiran-2-yl)propan-2-ol (19482-44-1) + 2-methyl-3-buten-2-ol (115-18-4) + 2-hydroperoxy-2-methyl-3-butene (15315-30-7) + acetone (67-64-1)

Guidance literature:

2-methyl-but-2-ene; With tert.-butylhydroperoxide; aluminum tri-tert-butoxide; In benzene; at 20 ℃; for 24h;

With sulfuric acid; In diethyl ether; Further byproducts given. Title compound not separated from byproducts;

DOI:10.1023/A:1012357318443

Reference yield:

3-Methyl-1-butene (563-45-1) → 2-isopropyloxirane (1438-14-8) + 2-methyl-3-buten-2-ol (115-18-4) + 2-hydroperoxy-2-methyl-3-butene (15315-30-7)

Guidance literature:

With air; Cumene hydroperoxide; at 100 ℃; for 2h; under 15001.2 Torr; Product distribution; also in the presence of Mo, Co and V-binetallic catalyst system;

Reference yield: 100.0%

1-methyl-1-phenylethyl alcohol (617-94-7) + 2-hydroperoxy-2-methyl-3-butene (15315-30-7) + 5% by weight-perchloric acid → α-(2-methyl-3-buten-2-ylperoxy)isopropylbenzene (118022-49-4)

Guidance literature:

In water;

upstream raw materials:

3-Methyl-1-butene

2-methyl-but-2-ene

Downstream raw materials:

2-methyl-3-buten-2-ol

α-(2-methyl-3-buten-2-ylperoxy)isopropylbenzene