15316-91-3

Basic information

• Product Name: N-ALLYL-O-TOLUIDINE
• Synonyms: N-ALLYL-ORTHO-TOLUIDINE;N-ALLYL-O-TOLUIDINE;Allylorthotoluidine;N-Allyl-orthio-toluidine
• CAS NO: 15316-91-3
• Molecular Formula: C₁₀H₁₃N
• Molecular Weight: 147.22
• Product Categories: monomer
• Mol File: 15316-91-3.mol
• Article Data: 16

Chemical Properties

• Boiling Point: 240.8 °C at 760 mmHg
• Flash Point: 99.8 °C
• Appearance: /
• Density: 0.96 g/cm³
• Vapor Pressure: 0.0373mmHg at 25°C
• Refractive Index: 1.561
• CAS DataBase Reference: N-ALLYL-O-TOLUIDINE(CAS DataBase Reference)
• NIST Chemistry Reference: N-ALLYL-O-TOLUIDINE(15316-91-3)
• EPA Substance Registry System: N-ALLYL-O-TOLUIDINE(15316-91-3)

Safety Data

• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36/37/39
• Hazardous Substances Data: 15316-91-3(Hazardous Substances Data)

Usage

General Description

N-Allyl-O-toluidine is a chemical compound with the molecular formula C10H13N. It is a derivative of toluene and allylamine, and it has a pale yellow color. N-ALLYL-O-TOLUIDINE is primarily used in the production of agrochemicals, pharmaceuticals, and rubber accelerator chemicals. It is also used in the synthesis of dyes and pigments. N-Allyl-O-toluidine is a flammable liquid with a strong, pungent odor, and it should be handled with caution due to its potential health hazards. It is important to follow safety guidelines when working with this chemical, including using appropriate protective equipment and storage practices.

InChI:InChI=1/C10H13N/c1-3-8-11-10-7-5-4-6-9(10)2/h3-7,11H,1,8H2,2H3

Upstream product

• 106-95-6 allyl bromide 
• 95-53-4 o-toluidine 
• 53443-78-0 2-methyl-N-prop-2-yn-1-yl-benzenamine 
• 107-18-6 allyl alcohol 
• 74965-31-4 N-(tert-butoxycarbonyl)-o-toluidine 
• 102-70-5 Triallylamine 
• 88-72-2 1-methyl-2-nitrobenzene 
• 2622-05-1 allylmagnesium bromide 

Downstream Products

• 1431884-74-0 C₁₅H₁₇NO₂ 
• 1431971-98-0 C₁₅H₁₇NO 
• 1257292-13-9 N-(2-allyl-6-methylphenyl)-4-methylbenzenesulfonamide 
• 83627-55-8 2-methyl-N-propylaniline 
• 41378-30-7 1-(2-methylphenyl)pyrrolidine 
• 67103-24-6 C₂₁H₂₀N₂O₄ 
• 57375-56-1 N-Ethoxycarbonyl-3-(N-allyl-o-tolylcarbamoyloxy)anilin 
• 55239-90-2 C₁₁H₁₂ClNO 

Relevant articles and documents

Ruthenium-catalyzed synthesis of 2-ethyl-3-methylquinolines from anilines and triallylamine

Anilines react with triallylamine in dioxane at 180°C in the presence of a catalytic amount of ruthenium chloride and triphenylphosphine together with tin(II) chloride dihydrate to afford the corresponding 2-ethyl-3- methylquinolines in good yields.

Copper(ii)-hydroxide facilitated C-C bond formation: The carboxamido pyridine system: Versus the methylimino pyridine system

A copper(ii)-hydroxide-induced carbon-carbon bond formation reaction is explored with the synthesis of an asymmetric carboxamido-methylimino pyridine Cu(i) complex of [CuI(py(N-CO)(NC-C)ph2Me2)2]- (12). Two imine-methyl groups are coupled to form a bridge

One-pot Construction of Difluorinated Pyrrolizidine and Indolizidine Scaffolds via Copper-Catalyzed Radical Cascade Annulation

A convenient approach to the synthesis of diverse difluorinated nitrogen-containing polycycles via a copper-catalyzed radical cascade annulation of amine-containing olefins and ethyl bromodifluoroacetate was developed. Three new bonds, including a Csp3 ?CF2 and two C?N bonds, are forged simultaneously in this strategy. Through this strategy, a series of difluorinated pyrrolizidine and indolizidine derivatives have been conveniently synthesized in good yields. (Figure presented.).