1531626-77-3

Upstream product

• 1309113-14-1 (E)-tert-butyl[(6-{[(4-methoxybenzyl)oxy]methyl}-4,4-dimethylhepta-2,6-dien-1-yl)oxy]dimethylsilane 
• 1309113-16-3 (E)-7-[(tert-butyldimethylsilyl)oxy]-4,4-dimethyl-2-methylenehept-5-en-1-ol 
• 1309113-21-0 (R,E)-(2-{5-[(tert-butyldimethylsilyl)oxy]-2,2-dimethylpent-3-en-1-yl}oxiran-2-yl)methanol 
• 1309113-23-2 (R,E)-7-[(tert-butyldimethylsilyl)oxy]-2,4,4-trimethylhept-5-ene-1,2-diol 
• 1309113-24-3 (R,E)-7-{[(tert-butyldimethylsilyl)oxy]-2-[4-methoxybenzyl]oxy}-2,4,4-trimethylhept-5-en-1-ol 
• 1309113-25-4 (R,E)-7-[(tert-butyldimethylsilyl)oxy]-2-[(4-methoxybenzyl)oxy]-2,4,4-trimethylhept-5-enal 
• 1309113-26-5 tert-butyl {(R,2E,7E,9E)-6-[(4-methoxybenzyl)oxy]-4,4,6,9-tetramethyl-12-(trimethylsilyl)dodeca-2,7,9-trien-11-yn-1-yloxy}dimethylsilane 
• 1531626-39-7 (R,2E,7E,9E)-6-[(4-methoxybenzyl)oxy]-4,4,6,9-tetramethyldodeca-2,7,9-trien-11-yn-1-ol 
• 1531626-55-7 [4-(benzyldimethylsilyl)phenyl]{(1R,3aS,4R,5S,7aR)-5-ethynyl-1-[(4-methoxybenzyl)oxy]-1,3,3,6-tetramethyl-2,3,3a,4,5,7a-hexahydro-1H-inden-4-yl}methanone 
• 1531626-58-0 [4-(benzyldimethylsilyl)phenyl][(1R,3aS,4R,5S,7aR)-5-ethynyl-1-hydroxy-1,3,3,6-tetramethyl-2,3,3a,4,5,7a-hexahydro-1H-inden-4-yl]methanone 
• 1531626-67-1 (1R,3aR,4R,5S,7aR)-4-(R)-[4-(benzyldimethylsilyl)phenyl](hydroxymethyl)-5-ethynyl-1,3,3,6-tetramethyl-2,3,3a,4,5,7a-hexahydro-1H-inden-1-ol 
• 67-56-1 methanol 
• 1531626-73-9 (1R,3aR,4R,5S,7aR)-5-ethynyl-4-[(R)-hydroxy(4-hydroxyphenyl)methyl]-1,3,3,6-tetramethyl-2,3,3a,4,5,7a-hexahydro-1H-inden-1-ol 
• 1309113-09-4 methyl 4-{[(4-methoxybenzyl)oxy]methyl}-2,2-dimethylpent-4-enoate 

Relevant academic research and scientific papers

Total synthesis of the antibiotic Elansolid B1

The antibiotic elansolid B1 was prepared by a convergent strategy that relied on a highly diastereoselective, biomimetic intramolecular Diels-Alder cycloaddition (IMDA) that furnished the tetrahydroindane unit. Other key features are a double Sonogashira cross-coupling and a substratecontrolled Yamamoto aldol reaction.