153165-21-0Relevant articles and documents
High temperature radical cyclization anomalies in the tandem enediyne-bis-radical cyclization
Grissom, Janet Wisniewski,Calkins, Trevor L.,Huang, Dahai,McMillen, Heidi
, p. 4635 - 4650 (2007/10/02)
Previous reports have shown that the thermolysis of aromatic enediynes containing radical accepting tethers will undergo tandem enediyne-radical cyclizations. Herein will be reported several examples of the tandem enediyne-bis-radical cyclization where no
Synthetic studies of the tandem enediyne-mono- and bis-radical cyclizations
Grissom, Janet Wisniewski,Calkins, Trevor L.,Egan, Miles
, p. 11744 - 11752 (2007/10/02)
The readily synthesized enediynes 12a-j possessing a tethered olefin radical acceptor can participate in a tandem enediyne-radical cyclization to yield dihydrobenzindene derivatives 14a-j. In the present study, the scope of this reaction was expanded to i