153198-58-4

Basic information

• Product Name: rac-(E)-1-chloro-7-(methoxycarbonyl)amino-8-(trityloxy)-2-octene
• Synonyms: rac-(E)-1-chloro-7-(methoxycarbonyl)amino-8-(trityloxy)-2-octene
• CAS NO: 153198-58-4
• Molecular Weight: 478.031
• Mol File: 153198-58-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: rac-(E)-1-chloro-7-(methoxycarbonyl)amino-8-(trityloxy)-2-octene(CAS DataBase Reference)
• NIST Chemistry Reference: rac-(E)-1-chloro-7-(methoxycarbonyl)amino-8-(trityloxy)-2-octene(153198-58-4)
• EPA Substance Registry System: rac-(E)-1-chloro-7-(methoxycarbonyl)amino-8-(trityloxy)-2-octene(153198-58-4)

Safety Data

• Hazardous Substances Data: 153198-58-4(Hazardous Substances Data)

Upstream product

• 157330-99-9 rac-(E)-ethyl 7-(methoxycarbonyl)amino-8-(trityloxy)-2-octenoate 
• 157330-95-5 rac-6-bis(ethylthio)-2-(mesyloxy)-1-(trityloxy)hexane 
• 157330-98-8 rac-6-bis(ethylthio)-2-(methoxycarbonyl)amino-1-(trityloxy)hexane 
• 157330-96-6 rac-2-azido-6-bis(ethylthio)-1-(trityloxy)hexane 
• 157330-97-7 5,5-Bis-ethylsulfanyl-1-trityloxymethyl-pentylamine 
• 157330-94-4 rac-6-bis(ethylthio)-2-hydroxy-1-(trityloxy)hexane 
• 157381-02-7 rac-6-bis(ethylthio)-1,2-dihydroxyhexane 
• 69891-85-6 4-(2,2-dimethyl-[1,3]-dioxolan-4-yl)-butyraldehyde 
• 76-83-5 trityl chloride 
• 106-69-4 hexane-1,2,6-triol 
• 14739-10-7 4-(2,2-dimethyl-1,3-dioxolane-4-yl)-1-butanol 
• 157331-00-5 rac-(E)-7-(methoxycarbonyl)amino-8-(trityloxy)-2-octen-1-ol 

Relevant articles and documents

Stereoselective total syntheses of (-)-desoxoprosopinine and (-)-desoxoprosophylline: Palladium(0)-catalyzed intramolecular N-alkylation for the key piperidine ring formation

Intramolecular N-alkylation of D-glucose-derived substrate 21E proceeded in an S(N)2' mode smoothly in the presence of a Pd(0) catalyst and n-Bu4NI. The major cyclization product, a 2,6-dialkylated piperidine 22t, was effectively converted into the title alkaloids.