153223-32-6

Upstream product

• 98-88-4 benzoyl chloride 
• 20701-61-5 ethyl 4,6-O-benzylidene-1-thio-β-D-glucopyranoside 
• 142924-31-0 S-ethyl 4,6-O-benzylidene-1-thio-α-D-mannopyranoside 

Downstream Products

• 187159-75-7 methyl O-(2,3-di-O-benzoyl-4,6-O-benzylidene-α-D-mannopyranosyl)-(1->3)-2-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside 
• 187159-78-0 methyl O-(2,3-di-O-benzoyl-4,6-O-benzylidene-α-D-mannopyranosyl)-(1->3)-O-(4,6-O-benzylidene-α-D-mannopyranosyl)-(1->3)-2-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside 
• 187218-12-8 (2R,4aR,6R,7S,8R,8aS)-6-((2R,4aR,6S,7S,8S,8aR)-7-Benzyloxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol 
• 153185-22-9 2-(p-trifluoroacetamidophenyl)ethyl 2,3-di-O-benzoyl-4,6-O-benzylidene-α-D-mannopyranoside 

Relevant academic research and scientific papers

SYNTHESIS OF OLIGOSACCHARIDES CORRESPONDING TO STRUCTURES FOUND IN CAPSULAR POLYSACCHARIDES OF CRYPTOCOCCUS NEOFORMANS. PART 1.

Syntheses are described of two trisaccharides, 2-(p-trifluoroacetamidophenyl)ethyl O-(β-D-xylopyranosyl)-(1->2)-O-(α-D-mannopyranosyl)-(1->3)α-D-mannopyranoside (10) and 2-(p-trifluoroacetamidophenyl)ethyl O-(α-D-mannopyranosyl)-(1->3)-O-(β-D-xylopyranos

PARTIAL SUBSTITUTION OF THIOGLYCOSIDES BY PHASE TRANSFER CATALYZED BENZOYLATION AND BENZYLATION

Partial substitution by phase transfer catalysis giving monobenzoylated and monobenzylated products from 2,3- and from 4,6-diols in ethyl 1-thio-D-hexopyranosides with the β-gluco, β-galacto- and α-manno-configurations are described.Two disaccharide thiog