153289-10-2Relevant academic research and scientific papers
CHLORINATION OF ALLYL COMPOUNDS
Obushak, N. D.,Karpyak, V. V.,Ganushchak, N. I.,Koval'chuk, E. P.,Tikhonov, V. P.
, p. 1149 - 1156 (2007/10/02)
Allyl halides, allyl isothiocyanate, allylbenzene and allyl acetone form chloroarylation products with aryldiazonium chloride under cupro- or ferrocatalysis conditions.The activity of compounds containing the allyl group differs in this reaction.Allyl iod
THIOCYANATO- AND CHLOROARYLATION OF ALLYL CHLORIDE AND BROMIDE
Grishchuk, B. D.,Gorbovoi, P. M.,Ganushchak, N. I.,Brush, D. M.,Kudrik, E. Ya.
, p. 1156 - 1158 (2007/10/02)
We showed by the example of thiocyanato- and chloroarylation of allyl chloride and bromide that the shielding of the double bond of an olefin from the influence of electron-acceptor groups does not favor the reaction of anion-arylation. 2-Aryl-1-chloromethyl(bromomethyl)ethyl thiocyanates were synthesized by the reaction of aromatic aryldiazonium tetrafluoroborates with allyl chloride or bromide in the presence of thiocyanates or chlorides of alkali metals.
