153397-50-3Relevant academic research and scientific papers
Rearrangement of cis- and trans-2-Methyl-1-(substituted phenyl)isoindolinium 2-Methylides
Sakuragi, Akira,Shirai, Naohiro,Sato, Yoshiro,Kurono, Yukihisa,Hatano, Keiichiro
, p. 148 - 153 (2007/10/02)
Fluoride ion induced desilylation of cis-2-methyl-1-(substituted phenyl)-2-isoindolinium iodides cis-5 gave mixtures of the Sommelet-Hauser rearrangement products 7 and the Stevens products 8 in a ratio about 8.5:1.5.Similar treatments of the trans-isomer (trans-5) afforded exclusively 8.The pathways of the ylide rearrangement are discussed.
