15344-29-3Relevant academic research and scientific papers
A facile synthesis of α-fluoro ketones catalyzed by [Cp*IrCl2]2
Ahlsten, Nanna,Bartoszewicz, Agnieszka,Agrawal, Santosh,Martin-Matute, Belen
, p. 2600 - 2608 (2011)
Allylic alcohols are isomerized into enolates (enols) by [Cp*IrCl2]2. The enolates react with Selectfluor present in the reaction media. This method produces α-fluoro ketones as single constitutional isomers in high yields. Georg Thieme Verlag Stuttgart. New York.
Ir-catalysed formation of C-F bonds. From allylic alcohols to α-fluoroketones
Ahlsten, Nanna,Martin-Matute, Belen
supporting information; experimental part, p. 8331 - 8333 (2011/09/12)
A novel iridium-catalysed tandem isomerisation/C-F bond formation from allylic alcohols and Selectfluor to prepare α-fluorinated ketones as single constitutional isomers is reported.
