Synthesis p. 2600 - 2608 (2011)
Update date:2022-08-04
Topics:
Ahlsten, Nanna
Bartoszewicz, Agnieszka
Agrawal, Santosh
Martin-Matute, Belen
Allylic alcohols are isomerized into enolates (enols) by [Cp*IrCl2]2. The enolates react with Selectfluor present in the reaction media. This method produces α-fluoro ketones as single constitutional isomers in high yields. Georg Thieme Verlag Stuttgart. New York.
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