153476-59-6

Basic information

• Product Name: (2-Bromo-allyl)-phenethyl-trimethylsilanyl-amine
• Synonyms: (2-Bromo-allyl)-phenethyl-trimethylsilanyl-amine
• CAS NO: 153476-59-6
• Molecular Weight: 312.325
• Mol File: 153476-59-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2-Bromo-allyl)-phenethyl-trimethylsilanyl-amine(CAS DataBase Reference)
• NIST Chemistry Reference: (2-Bromo-allyl)-phenethyl-trimethylsilanyl-amine(153476-59-6)
• EPA Substance Registry System: (2-Bromo-allyl)-phenethyl-trimethylsilanyl-amine(153476-59-6)

Safety Data

• Hazardous Substances Data: 153476-59-6(Hazardous Substances Data)

Upstream product

• 64-04-0 phenethylamine 
• 75-77-4 chloro-trimethyl-silane 
• 72551-18-9 N-(2-phenethyl)-2-bromo-2-propenylamine 

Relevant articles and documents

Preparation and Reactivity of New β-Nitrogen-Functionalized Vinylic Organolithium Compounds from Secondary Aliphatic Allylamines

Two new types of β-nitrogen-functionalized vinylic organolithium compounds have been prepared from secondary aliphatic allylamines through the temporary silylation of the amino group.The monoanionic intermediates 4, stable at -80 deg C, are generated by a bromine-lithium exchange reaction and the dianionic derivatives 2, stable at room temperature, by a tin-lithium transmetalation reaction.Both types of organolithium compounds react with different electrophiles giving functionalized allylamines 7 and 10-27.Moreover, dianionic derivatives 30,33 can be prepared directly by bromine-lithium exchange when the β-elimination reaction of hydrogen bromide in the lithium 2-bromoallylamide is structurally hindered.Additionally, a novel type of anionic 1,3-rearrangement of a trimethylsilyl group from nitrogen to carbon is described.