15355-79-0

Upstream product

• 103-72-0 phenyl isothiocyanate 
• 103-01-5 N-Phenylglycine 
• 79-11-8 chloroacetic acid 
• 102-08-9 N,N-diphenylthiourea 
• 105-39-5 chloroacetic acid ethyl ester 
• 62-53-3 aniline 

Downstream Products

• 128939-46-8 1,3-Diphenyl-5-[1-thiophen-2-yl-meth-(Z)-ylidene]-2-thioxo-imidazolidin-4-one 
• 128939-49-1 7-Furan-2-yl-1,3,5-triphenyl-2-thioxo-1,2,3,7-tetrahydro-pyrano[2,3-d]imidazole-6-carbonitrile 
• 128939-47-9 5-Amino-7-furan-2-yl-1,3-diphenyl-2-thioxo-1,2,3,7-tetrahydro-pyrano[2,3-d]imidazole-6-carbonitrile 
• 3157-03-7 1,3-diphenyl imidazolidine-2,4-dione 
• 18478-44-9 1,3-diphenylimidazole-2-thione 
• 1040551-08-3 (Z)-1,3-diphenyl-5-(benzoylmethylene)-4-oxo-2-thioxoimidazolidine 
• 128939-48-0 5-Amino-1,3-diphenyl-7-thiophen-2-yl-2-thioxo-1,2,3,7-tetrahydro-pyrano[2,3-d]imidazole-6-carbonitrile 
• 82754-83-4 5-Amino-7-(4-nitro-phenyl)-1,3-diphenyl-2-thioxo-1,2,3,7-tetrahydro-pyrano[2,3-d]imidazole-6-carbonitrile 
• 82754-82-3 5-Amino-1,3,7-triphenyl-2-thioxo-1,2,3,7-tetrahydro-pyrano[2,3-d]imidazole-6-carbonitrile 
• 332838-23-0 5-[1-(3,4-Dimethoxy-phenyl)-meth-(E)-ylidene]-1,3-diphenyl-2-thioxo-imidazolidin-4-one 
• 129049-01-0 5-[1-(3-Nitro-phenyl)-meth-(E)-ylidene]-1,3-diphenyl-2-thioxo-imidazolidin-4-one 
• 332838-18-3 1,3-diphenyl-5-(2-chlorobenzylidene)-2-thiohydantoin 
• 332838-22-9 5-[1-(4-Fluoro-phenyl)-meth-(E)-ylidene]-1,3-diphenyl-2-thioxo-imidazolidin-4-one 
• 82754-84-5 1,3,5,7-Tetraphenyl-2-thioxo-1,2,3,7-tetrahydro-pyrano[2,3-d]imidazole-6-carbonitrile 

Relevant academic research and scientific papers

Oxidative desulfurization of azole-2-thiones with benzoyl peroxide: Syntheses of ionic liquids and other azolium salts

1-Alkyl-3-methylimidazole-2-thiones were prepared from amino esters in one pot and converted to inherently halide-free 1-alkyl-3-methylimidazolium benzoates by oxidation with benzoyl peroxide followed by a novel anion exchange. Also reported are the outcomes of exchanges with other anions, acidifications of the imidazolium benzoates to other salts, and extension of the method to the syntheses of 1,3-diphenylimidazolium and 3-methyl- and -butylthiazolium salts. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.

Synthesis of thiazol, thiazinan, thiadiazin, thiazolidin, triazine, thioxo-pyrimidin and thioxo-imidazolidine by inter-intra molecular cyclization

Syntheses of five and six membered heterocyclic derivatives by the reaction of disubstituted thiocarbamides with interintramolecular cyclizations in catalyst free condition have been reported. The simple product isolation without column, good yields under mild condition, and applicable green matrix are the advantages of present protocol.

Synthesis of thiohydantoins under one-pot three-component solvent-free conditions

A direct and efficient one-pot three-component synthesis protocol was developed for the synthesis of thiohydantoins from readily and widely available substrates (isothiocyanates, ethyl chloroacetate, and amines) employing solvent-free conditions.

Pesticidal thiohydantoin compositions

The invention describes a method for inhibiting the growth of pests comprising applying thereto a pesticidal amount of a compound of the formula STR1 wherein R1, and R2 are independently hydrogen, substituted or unsubstituted lower alkyl, cycloalkyl, phenyl, or alkenyl, and halogen, amino or hydroxy groups, R3 and R4 are independently hydrogen or substituted or unsubstituted lower alkyl, R5 is hydrogen, substituted or unsubstituted lower alkyl, cycloalkyl or phenyl, and naphthyl groups; pesticidal compositions containing at least one of said compounds; and novel thiohydantoin compounds having pesticidal activity.

Carbon-13 NMR Studies of 1-Aryl-3-phenyl-2-thioxo-4-imidazolidinones Conformational Isomerism and Substituent Effects

Characteristic (13)C chemical shift ranges and substituent shifts of heterocyclic ring carbon atoms have been identified for a number of 1-aryl-3-phenyl-2-thioxo-4-imidazolidinones. (13)C NMR spectra may be used to detect slow internal rotation about the