18478-44-9Relevant academic research and scientific papers
Oxidative desulfurization of azole-2-thiones with benzoyl peroxide: Syntheses of ionic liquids and other azolium salts
Wolfe, Derek M.,Schreiner, Peter R.
, p. 2825 - 2838 (2008/03/13)
1-Alkyl-3-methylimidazole-2-thiones were prepared from amino esters in one pot and converted to inherently halide-free 1-alkyl-3-methylimidazolium benzoates by oxidation with benzoyl peroxide followed by a novel anion exchange. Also reported are the outcomes of exchanges with other anions, acidifications of the imidazolium benzoates to other salts, and extension of the method to the syntheses of 1,3-diphenylimidazolium and 3-methyl- and -butylthiazolium salts. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.
Dication Disulfides by Reaction of Thioureas and Related Compounds with Trifluoromethanesulfonic Anhydride. The Role of Triflic Anhydride as an Oxidizing Agent
Maas, Gerhard,Stang, Peter J.
, p. 1606 - 1610 (2007/10/02)
Interaction of thiourea and substituted thioureas with trifluoromethanesulfonic acid anhydride in methylene chloride results in stable dication disulfide salts (R2N)2+CSSC+(NR2)2*2CF3SO3-.These results indicate that trifli
