153588-53-5

Basic information

• Product Name: {InCl₃(C₆H₅C(O)CH₃)2}
• CAS NO: 153588-53-5
• Molecular Weight: 461.481
• Mol File: 153588-53-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {InCl₃(C₆H₅C(O)CH₃)2}(CAS DataBase Reference)
• NIST Chemistry Reference: {InCl₃(C₆H₅C(O)CH₃)2}(153588-53-5)
• EPA Substance Registry System: {InCl₃(C₆H₅C(O)CH₃)2}(153588-53-5)

Safety Data

• Hazardous Substances Data: 153588-53-5(Hazardous Substances Data)

Upstream product

• 10025-82-8 indium(III) chloride 

Relevant articles and documents

Evidence on Ligand Strengths from the Crystal Structures of , , 2>*PhCHO and from Dimethylformamide (dmf), Dimethylacetamide (dma), Benzaldehyde and Acetophenone

X-Ray crystal structure determinations have been made for the fac octahedral complexes 1, 2 and 2>*PhCHO 3, from dimethylformamide (dmf), dimethylacetamide and benzaldehyde and the trigonal-bipyramidal complex 4 from acetophenone.The average In-O bond length for 3 is ca. 0.07 Angstroem greater than for 1 or 2.In 4, In-O is 0.07 Angstroem longer than that known for from tetramethylurea (tmu).An extension of the comparison to structures involving other ligands shows there to be a general correspondence between In-O bond lengths and ligand donor values.By contrast with the weak co-ordination of aldehydes and ketones, co-ordination of an amide is enhanced through polarisation.In the crystal of 3, individual molecules are paired, almost centrosymmetrically, with intermeshing of their PhCHO ligands.