1536478-77-9Relevant academic research and scientific papers
Rh2(II)-Catalyzed Ring Expansion of Cyclobutanol-Substituted Aryl Azides to Access Medium-Sized N-Heterocycles
Mazumdar, Wrickban,Jana, Navendu,Thurman, Bryant T.,Wink, Donald J.,Driver, Tom G.
supporting information, p. 5031 - 5034 (2017/05/04)
A new reactivity pattern of Rh2(II)-N-arylnitrenes was discovered that facilitates the synthesis of medium-sized N-heterocycles from ortho-cyclobutanol-substituted aryl azides. The key ring-expansion step of the catalytic cycle is both chemosel
