153827-83-9Relevant academic research and scientific papers
Enantioselective addition of diethylzinc to aldehydes with novel chiral C2-symmetric dimeric ligands
Okaniwa, Masanori,Yanada, Reiko,Ibuka, Toshiro
, p. 1047 - 1050 (2007/10/03)
Novel (S)-valinol-based chiral C2-2,2'-ethylenediiminodiethanol derivatives 4a and 4b have been synthesized and used as chiral catalysts in the enantioselective addition of diethylzinc to aldehydes. (R)-1- Phenylpropanol has been obtained in up
Factors influencing the stereoselectivity in the cycloaddition of imino-dienophiles derived from amino ethers, amino alcohols, and amino acid esters
Devine,Reilly,Oh
, p. 5827 - 5830 (2007/10/02)
Imino dienophiles derived from amino ethers, amino alcohols and amino esters undergo Lewis acid promoted cycloaddition with Danishefsky's diene. Cyclic chelation between the imine and oxygen atom increases the stereoselectivity of the reaction.
