153831-44-8

Basic information

• Product Name: 2,3-(cyclopenten-exo-3',5'-diyl)-N-(2,4-dinitrophenoxy)succinimine
• Synonyms: 2,3-(cyclopenten-exo-3',5'-diyl)-N-(2,4-dinitrophenoxy)succinimine
• CAS NO: 153831-44-8
• Molecular Weight: 345.268
• Mol File: 153831-44-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,3-(cyclopenten-exo-3',5'-diyl)-N-(2,4-dinitrophenoxy)succinimine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3-(cyclopenten-exo-3',5'-diyl)-N-(2,4-dinitrophenoxy)succinimine(153831-44-8)
• EPA Substance Registry System: 2,3-(cyclopenten-exo-3',5'-diyl)-N-(2,4-dinitrophenoxy)succinimine(153831-44-8)

Safety Data

• Hazardous Substances Data: 153831-44-8(Hazardous Substances Data)

Upstream product

• 97-00-7 1-chloro-2,4-dinitro-benzene 
• 216392-97-1 (3aR,4R,7S,7aS)-2-hydroxy-3a,4,7,7a-tetrahydro-1H-4,7-methanoisoindole-1,3(2H)-dione (N-hydroxy-5-exo-norbornene-2,3-dicarboximide) 

Downstream Products

• 839-93-0 1-(2,4-dinitrophenyl)piperidine 
• 216392-97-1 (3aR,4R,7S,7aS)-2-hydroxy-3a,4,7,7a-tetrahydro-1H-4,7-methanoisoindole-1,3(2H)-dione (N-hydroxy-5-exo-norbornene-2,3-dicarboximide) 
• 51-28-5 2,4-Dinitrophenol 

Relevant articles and documents

Base-catalysed nucleophilic aromatic substitution reaction: Difference in reactivity between endo- and exo-2,3-(cyclopenten-3',5'-diyl)-N-(2",4"-dinitrophenoxy)succinimides with hydroxide ion and piperidine

The reaction of 2,3-(cyclopenten-endo-3',5'-diyl)-N-(2",4"-dinitrophenoxy)succinimide (1) with hydroxide ion and piperidine in aq. acetonitrile is base-catalysed.The exo-isomer (2) reacts at a faster rate than the endo-isomer (1).The rate of the reaction in various acetonitrile-water media decreases with a decrease in water concentration for both hydroxide ion and piperidine in the case of endo-isomer and only in respect of hydroxide ion in the case of exo-isomer.The reaction rate with piperidine in the case of exo-isomer, however, increases with a decrease in the percentage of water.The mechanistic interpretation is given.