153864-60-9

Basic information

• Product Name: Pentanedioic acid, 2-(phenylhydrazono)-, diethyl ester, (Z)-
• CAS NO: 153864-60-9
• Molecular Formula: C15H20N2O4
• Molecular Weight: 292.335
• Mol File: 153864-60-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pentanedioic acid, 2-(phenylhydrazono)-, diethyl ester, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Pentanedioic acid, 2-(phenylhydrazono)-, diethyl ester, (Z)-(153864-60-9)
• EPA Substance Registry System: Pentanedioic acid, 2-(phenylhydrazono)-, diethyl ester, (Z)-(153864-60-9)

Safety Data

• Hazardous Substances Data: 153864-60-9(Hazardous Substances Data)

Upstream product

• 5965-53-7 diethyl 2-ketoglutarate 
• 100-63-0 phenylhydrazine 

Downstream Products

• 5965-53-7 diethyl 2-ketoglutarate 
• 35818-60-1 2-oxoglutaric acid 1-ethyl ester 

Relevant articles and documents

Oxidation of hydrazones by hypervalent organoiodine reagents: Regeneration of the carbonyl group and facile syntheses of α-acetoxy and α-alkoxy azo compounds

Various hydrazone derivatives of α-keto esters were prepared. The carbonyl group was readily regenerated in high yield from phenylhydrazones through oxidative hydrolysis using hypervalent organoiodine(III) reagents either bis(trifluoroacetoxy)-iodobenzene (BTIB) in aqueous acetonitrile or hydroxy(tosyloxy)iodobenzene (HTIB) in chloroform. α-Acotxy phenyl- or methylazo compounds were readily synthesized by oxidation of the corresponding hydrazones with iodobenzene diacetate (IBDA) in dichloromethane or acetic acid. α-Methoxy phenyl- or methylazo compounds were also prepared by oxidation of the hydrazones in methanol. The mechanisms of the oxidation reactions are discussed.