153908-42-0

Basic information

• Product Name: iodo(phenylseleno)methane
• Synonyms: iodo(phenylseleno)methane
• CAS NO: 153908-42-0
• Molecular Weight: 296.997
• Mol File: 153908-42-0.mol

Chemical Properties

• CAS DataBase Reference: iodo(phenylseleno)methane(CAS DataBase Reference)
• NIST Chemistry Reference: iodo(phenylseleno)methane(153908-42-0)
• EPA Substance Registry System: iodo(phenylseleno)methane(153908-42-0)

Safety Data

• Hazardous Substances Data: 153908-42-0(Hazardous Substances Data)

Upstream product

• 20343-90-2 bis(phenylseleno)methane 
• 83442-19-7 chloromethyl phenylselenide 

Downstream Products

• 137720-65-1 C₂₅H₃₂O₃SSe 
• 137720-64-0 C₂₅H₃₂O₃SSe 
• 137792-20-2 C₂₅H₃₂O₃SSe 
• 137720-60-6 C₂₀H₃₀O₄ 
• 137720-59-3 C₂₆H₃₄O₄Se 
• 335164-92-6 3-phenyl-1-[2-[(phenylseleno)methoxy]phenyl]-2-propyn-1-ol 
• 181134-87-2 bis(1,1-dimethylethyl)[[3-phenyl-1-[2-[(phenylseleno)methoxy]phenyl]-2-propynyl]oxy]silane 
• 335165-15-6 1-[2-[(phenylseleno)methoxy]phenyl]-2-propyn-1-ol 
• 335165-14-5 1-[2-[(phenylseleno)methoxy]phenyl]-3-trimethylsilyl-2-propyn-1-ol 

Relevant articles and documents

Facile C-Se and C-S Bond Cleavages in Diorganyl Selenides and Sulfides by Iodine

The C-Se and C-S bonds in ArSeCH2SeAr, PhCH2SeCH2SeCH2Ph, (p-t-Bu-C6H4SeCH2)2, 1,8-(MeSe)2C10H6, PhCH2SeMe, PhSCH2SPh, and PhCH2SCH2SCH2Ph are easily cleaved by iodine, while those of PhSe(CH2)3SePh, 1-MeSeC10H7, PhSeCH2I, and PhCH2SMe are not.The driving force of the reaction is also discussed.

Preparation of polycyclic systems by sequential 5-exo-digonal radical cyclization, 1,5-hydrogen transfer from silicon, and 5-endo-trigonal cyclization

Radicals of type 1 undergo 5-exo diagonal cyclization, and the resulting vinyl radical abstracts hydrogen from silicon to afford a silicon-centered radical. This radical closes in a 5-endo trigonal manner to generate radicals of type 4, which are reduced