153993-00-1

Basic information

• Product Name: tert-Butyl-[3-(4-methoxy-phenyl)-1-methylene-propoxy]-dimethyl-silane
• Synonyms: tert-Butyl-[3-(4-methoxy-phenyl)-1-methylene-propoxy]-dimethyl-silane
• CAS NO: 153993-00-1
• Molecular Weight: 292.494
• Mol File: 153993-00-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: tert-Butyl-[3-(4-methoxy-phenyl)-1-methylene-propoxy]-dimethyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: tert-Butyl-[3-(4-methoxy-phenyl)-1-methylene-propoxy]-dimethyl-silane(153993-00-1)
• EPA Substance Registry System: tert-Butyl-[3-(4-methoxy-phenyl)-1-methylene-propoxy]-dimethyl-silane(153993-00-1)

Safety Data

• Hazardous Substances Data: 153993-00-1(Hazardous Substances Data)

Upstream product

• 3815-30-3 4-(4-methoxyphenyl)-3-buten-2-one 
• 123-11-5 4-methoxy-benzaldehyde 
• 104-20-1 4-(4-methoxyphenyl)-2-butanone 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 104-20-1 4-(4-methoxyphenyl)-2-butanone 
• 4133-34-0 7-methoxyl-2-tetralone 

Relevant articles and documents

New Intramolecular α-Arylation Strategy of Ketones by the Reaction of Silyl Enol Ethers to Photosensitized Electron Transfer Generated Arene Radical Cations: Construction of Benzannulated and Benzospiroannulated Compounds

Efficient intramolecular α-arylation of ketones is achieved by the reaction of silyl enol ethers to photosensitized electron transfer (PET) generated arene radical cations. The arene radical cations are generated by one-electron transfer from the excited state of the methoxy-substituted arenes to ground-state 1,4-dicyanonaphthalene (DCN). This arylation strategy has provided the unique opportunity of constructing five- (23), six- (18), seven- (25) and eight-membered (27) benzannulated as well as benzospiroannulated (34) compounds. The explanation for the formation of 27 has been advanced by considering the proximity between the arene radical cation and silyl enol ether due to the self-coiling in the aqueous environment.