154002-63-8Relevant academic research and scientific papers
Metal-, Photocatalyst-, and Light-Free Minisci C-H Alkylation of N-Heteroarenes with Oxalates
Dong, Jianyang,Wang, Zhen,Wang, Xiaochen,Song, Hongjian,Liu, Yuxiu,Wang, Qingmin
, p. 7532 - 7540 (2019/06/14)
Herein, we report a mild protocol for metal-, photocatalyst-, and light-free Minisci C-H alkylation reactions of N-heteroarenes with alkyl oxalates derived from primary, secondary, and tertiary alcohols. The protocol uses environmentally benign persulfate
Alkylation of Aromatic Heterocycles with Oxalic Acid Monoalkyl Esters in the Presence of Trivalent Iodine Compounds
Togo, Hideo,Aoki, Masahiko,Yokoyama, Masataka
, p. 1691 - 1694 (2007/10/02)
Aromatic heterocycles containing nitrogen atoms were easily alkylated with the half esters of oxalic acid, which were prepared from alcohols, in the presence of benzene via radical decarboxylative pathways.This is the first method for the alkylation of aromatic heterocycles with alcohols via the formation of half esters of oxalic acid.
