70894-19-8

Basic information

• Product Name: oxalic acid monomenthyl ester
• Synonyms: oxalic acid monomenthyl ester
• CAS NO: 70894-19-8
• Molecular Weight: 228.288
• Mol File: 70894-19-8.mol

Chemical Properties

• CAS DataBase Reference: oxalic acid monomenthyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: oxalic acid monomenthyl ester(70894-19-8)
• EPA Substance Registry System: oxalic acid monomenthyl ester(70894-19-8)

Safety Data

• Hazardous Substances Data: 70894-19-8(Hazardous Substances Data)

Upstream product

• 2216-51-5 (-)-menthol 
• 79-37-8 oxalyl dichloride 
• 117530-32-2 methyl-((1R)-menthyl)-oxalate 
• 144-62-7 oxalic acid 

Downstream Products

• 2085-26-9 bis[(1R,2S,5R)-2-isopropyl-5-methylcyclohexyl]oxalate 
• 154002-63-8 2-((1R,5R)-2-isopropyl-5-methylcyclohexyl)-4-methylquinoline 
• 16052-42-9 (1R,2S,5R)-menthyl chloride 
• 13371-12-5 neomenthyl chloride 
• 2085-26-9 ((1R)-menthyl)-((1S)-menthyl)-oxalate 
• 81529-62-6 (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl 2-chloro-2-oxoacetate 
• 500-00-5 3-p-menthene 

Relevant articles and documents

Metal-, Photocatalyst-, and Light-Free Minisci C-H Alkylation of N-Heteroarenes with Oxalates

Herein, we report a mild protocol for metal-, photocatalyst-, and light-free Minisci C-H alkylation reactions of N-heteroarenes with alkyl oxalates derived from primary, secondary, and tertiary alcohols. The protocol uses environmentally benign persulfate

Radical Deoxychlorination of Cesium Oxalates for the Synthesis of Alkyl Chlorides

A radical deoxychlorination of cesium oxalates has been developed for the preparation of hindered secondary and tertiary alkyl chlorides. The reaction tolerates a number of functional groups, including ketones, alcohols, and amides, and provides complementary reactivity to standard deoxychlorination reactions proceeding by heterolytic mechanisms. Preliminary studies demonstrate that the developed conditions can also be applied to deoxybromination and deoxyfluorination reactions.

Reductive Addition to Electron-deficient Olefins with Trivalent Iodine Compounds

(Diacyloxyiodo)arene was treated with electron-deficient olefins in the presence of hydrogen donor such as 1,4-cyclohexadiene to give the reductive addition products via alkyl radical through the radical decarboxylative pathway in good yields.Moreover, this system was able to generate either alkoxycarbonyl radicals or alkyl radicals with benzene, which was prepared from alcohol, oxalyl chloride, and (diacetoxyiodo)benzene via two steps, depending on reaction conditions.These radicals were also utilized for C-C bond formation with electron-deficient olefins.

Alkylation of Aromatic Heterocycles with Oxalic Acid Monoalkyl Esters in the Presence of Trivalent Iodine Compounds

Aromatic heterocycles containing nitrogen atoms were easily alkylated with the half esters of oxalic acid, which were prepared from alcohols, in the presence of benzene via radical decarboxylative pathways.This is the first method for the alkylation of aromatic heterocycles with alcohols via the formation of half esters of oxalic acid.