15403-12-0Relevant articles and documents
Si-N Heterodehydrocoupling with a Lanthanide Compound
Cibuzar, Michael P.,Waterman, Rory
supporting information, p. 4395 - 4401 (2019/01/03)
[La{N(SiMe3)2}3THF2] (1) is an effective precatalyst for the heterodehydrocoupling of silanes and amines. Coupling of primary and secondary amines with aryl silanes was achieved with a loading of 0.8 mol % of [L
Catalytic dehydrogenative Si-N coupling of pyrroles, indoles, carbazoles as well as anilines with hydrosilanes without added base
K?nigs, C. David F.,Müller, Maria F.,Aiguabella, Nuria,Klare, Hendrik F. T.,Oestreich, Martin
supporting information, p. 1506 - 1508 (2013/03/13)
A base-free, catalytic protocol for the dehydrogenative Si-N coupling of weakly nucleophilic N-H groups of heteroarenes or aryl-substituted amines with equimolar amounts of hydrosilanes is reported. Cooperative Si-H bond activation at a Ru-S bond generates a silicon electrophile that forms a Si-N bond prior to the N-H deprotonation by an intermediate Ru-H complex, only releasing H 2. The Royal Society of Chemistry 2013.
Synthesis and application of some dianilinosilanes, bis (trimethylsilyl) phenylenediamines and dialkyl benzo-1,3,2-diazasilolines as antioxidants
Ali, Hussein M.,El-Qurashi, Mohamed A. M.
, p. 521 - 529 (2007/10/03)
A number of dialkyl or diphenyl dianilinosilanes, bis (trimethylsilyl) phenylenediamines and dialkyl benzo-1,3,2-diazasilolines were synthesized and used as antioxidants for lubricating base oils. Thermal analysis methods (DSC, TG and DTG) and IR techniqu
