154079-07-9

Upstream product

• 24544-04-5 2,6-diisopropylbenzenamine 
• 544-92-3 copper(I) cyanide 

Downstream Products

• 156023-29-9 1-(2,6-diisopropylphenyl)-1-iminoethane 
• 1190631-05-0 Pd(N₃)(N,N'-dimethylbenzylamine)PMe₃(C=N-C₆H₃-2,6-i-Pr₂) 
• 1190631-07-2 Pd(N=C=N-2,6-C₆H₃-i-Pr₂)(N,N'-dimethylbenzylamine)PMe₃(C=N-C₆H₃-2,6-i-Pr₂) 

Relevant academic research and scientific papers

Aprotic diazotization in the presence of cuprous cyanide

In a procedure of extreme simplicity and rapidity a mixture of an aromatic primary amine, copper (I) cyanide and an alkyl nitrite in dimethyl sulphoxide yielded fair to moderate yields of the corresponding nitriles. Side processes observed were reduction (NH2&[H), nitration (NH2←NO2) and hydroxylation (NH2&[OH). In the case of polyhaloanilines halogen dance products could be detected.

Sterically Congested Molecules, 11. The 2,6-Diisopropylphenyl Substituent at C=C and C=N Groups

Two series of new compounds with sterically shielded, sp2-hybridized C-α atoms are prepared from bromo(chloro)-2,6-diisopropylbenzene.The α-(2,6-diisopropylphenyl) substituent common to all of them is used as an NMR-spectroscopic indicator for