1542-34-3Relevant articles and documents
Chlorination of aniline and methyl carbanilate by N-chlorosuccinimide and synthesis of 1,3,5-trichlorobenzene
Davis, Matthew C.
experimental part, p. 1100 - 1108 (2009/09/08)
Aniline undergoes regioselective trichlorination by N-chlorosuccinimide (NCS) in acetonitrile in good yield. The product 2,4,6-trichoroaniline was converted into 1,3,5-trichlorobenzene by reduction of its diazonium salt. Reaction of the methyl carbamate of aniline with NCS gave only the 2,4-dichlorophenyl carbamate. Copyright Taylor & Francis Group, LLC.