154228-83-8

Basic information

• Product Name: 1-(2-cyclohexen-1-yl)-4-methyl-1,2,4-triazolidine-3,5-dione
• Synonyms: 1-(2-cyclohexen-1-yl)-4-methyl-1,2,4-triazolidine-3,5-dione
• CAS NO: 154228-83-8
• Molecular Weight: 195.221
• Mol File: 154228-83-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-(2-cyclohexen-1-yl)-4-methyl-1,2,4-triazolidine-3,5-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-cyclohexen-1-yl)-4-methyl-1,2,4-triazolidine-3,5-dione(154228-83-8)
• EPA Substance Registry System: 1-(2-cyclohexen-1-yl)-4-methyl-1,2,4-triazolidine-3,5-dione(154228-83-8)

Safety Data

• Hazardous Substances Data: 154228-83-8(Hazardous Substances Data)

Upstream product

• 13274-43-6 4-methyl-1,2,4-triazoline-3,5-dione 
• 110-83-8 cyclohexene 
• 16312-79-1 4-methylurazole 

Downstream Products

• 270063-67-7 1-(2-cyclohexen-1-yl)-4-methyl-2-(2-oxo-2-phenylethyl)-1,2,4-triazolidine-3,5-dione 
• 1541-25-9 3-amino-1-cyclohexene 
• 33024-57-6 N-(2-cyclohexen-1-yl)-N'-methylurea 

Relevant articles and documents

Direct amination of olefins through sequential triazolinedione ene reaction and carbanion-assisted cleavage of the N-N urazole bond

(formula presented) Allylic amines 5 are obtained in 30-55% overall yields by the base-catalyzed hydrolysis of trialkylated allylic urazoles 3; the latter are prepared by the TAD ene reaction of the appropriate olefin and further N-alkylation with α-bromo

Ene Reaction of Triazolinediones with Alkenes. 2. Kinetics and Substituent Effects

The kinetic measurements for the reaction of 4-substituted-1,2,4-triazoline-3,5-diones (4-R-TD; R=Ph, Me, p-MeOC6H4, p-NO2C6H4) with alkenes have been undertaken.The reactivity of alkenes was found to be very sensitive to substituent effects.The effects of solvent and substituent on TD were small.In the reaction of TD with ene products, side reactions as well as second-step ene reactions were observed.The reactions of 1-alkyl-4-phenyl-1,2,4-triazolidine-3,5-diones were investigated, and the reaction products were isolated.