154367-73-4

Upstream product

• 5707-04-0 Phenylselenyl chloride 
• 563-63-3 silver(I) acetate 
• 154367-72-3 4-O-acetyl-3-O-((triethyl)silyl)-D-fucal 
• 134355-03-6 6-deoxy-D-glucal 
• 994-30-9 triethylsilyl chloride 

Downstream Products

• 154367-80-3 acetyl 4-O-acetyl-2-deoxy-2-(selenophenyl)-β-D-fuco-pyranoside 
• 154367-78-9 Acetic acid (2R,3R,4S,5R,6S)-6-((2R,3S,4S,5R,6S)-3-acetoxy-6-hydroxy-2-methyl-5-phenylselanyl-tetrahydro-pyran-4-yloxy)-4-(tert-butyl-dimethyl-silanyloxy)-5-phenylsulfanyl-2-(toluene-4-sulfonyloxymethyl)-tetrahydro-pyran-3-yl ester 
• 154367-79-0 Acetic acid (2R,3R,4S,5R,6S)-6-[(2R,3S,4S,5R,6S)-3-acetoxy-2-methyl-6-(naphthalen-2-yloxy)-5-phenylselanyl-tetrahydro-pyran-4-yloxy]-4-(tert-butyl-dimethyl-silanyloxy)-5-phenylsulfanyl-2-(toluene-4-sulfonyloxymethyl)-tetrahydro-pyran-3-yl ester 
• 154367-77-8 Acetic acid (2R,3R,4S,5R,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-((2R,3R,4S,5S,6R)-2,5-diacetoxy-6-methyl-3-phenylselanyl-tetrahydro-pyran-4-yloxy)-5-phenylsulfanyl-2-(toluene-4-sulfonyloxymethyl)-tetrahydro-pyran-3-yl ester 
• 154367-75-6 4-O-acetyl-3-O<3-O-((tert-butyldimethyl)silyl)-2,6-dideoxy-2-iodo-4-O-methyl-α-D-talo-pyranosyl>-2,6-dideoxy-2-(selenophenyl)-α-D-galacto-pyranose 
• 154367-76-7 2-naphthyl 4-O-acetyl-3-O<3-O-((tert-butyldimethyl)silyl)-2,6-dideoxy-2-iodo-4-O-methyl-α-D-talo-pyranosyl>-2,6-dideoxy-2-(selenophenyl)-β-D-galacto-pyranoside 

Relevant academic research and scientific papers

Studies on the synthesis of aureolic acid antibiotics: Highly stereoselective synthesis of aryl 2-deoxy-β-glycosides via the Mitsunobu reaction and synthesis of the olivomycin A-B disaccharide

The Mitsunobu reaction of phenols and 1,2-cis-2-thiophenyl-α-D-glycopyranoses or 1,2-cis-2-selenophenyl-α-D-glycopyranoses is a very effective method for the highly stereoselective synthesis of aryl 2-deoxy-β-D-glycosides. The equatorial 2-thiophenyl or 2

Synthesis of naphthyl A-B disaccharides corresponding to olivomycin A and mithramycin

Highly stereoselective syntheses of naphthyl disaccharides 4 and 5, which correspond to the A-B dissaccharide units of olivomycin A and mithramycin, are described.