563-63-3

Basic information

• Product Name: Silver acetate
• Synonyms: Aceticacid, silver(1+) salt (1:1);Silver acetate 99.99% trace Metals basis;Silver acetate purum p.a., >=99.0% (T);Silver acetate ReagentPlus(R), 99%;silver(1+) ion acetic acid;SILVER ACETATE;SILVER(I) ACETATE;ACETIC ACID SILVER SALT
• CAS NO: 563-63-3
• Molecular Formula: C₂H₃AgO₂
• Molecular Weight: 166.91
• EINECS: 209-254-9
• Product Categories: Organic-metal salt;metal acetate salt
• Mol File: 563-63-3.mol
• Article Data: 11

Chemical Properties

• Melting Point: decomposes [STR93]
• Boiling Point: 117.1°C at 760 mmHg
• Flash Point: 40°C
• Appearance: White to gray/Powder/Solid
• Density: 3.25
• Vapor Pressure: 13.9mmHg at 25°C
• Storage Temp.: Store below +30°C.
• Solubility: 10.2g/l
• Water Solubility: 10.2 g/L (20 ºC)
• Sensitive: Light Sensitive
• Stability: Stability Stable, but light sensitive. Incompatible with strong reducing agents.
• Merck: 14,8505
• BRN: 3595636
• CAS DataBase Reference: Silver acetate(CAS DataBase Reference)
• NIST Chemistry Reference: Silver acetate(563-63-3)
• EPA Substance Registry System: Silver acetate(563-63-3)

Safety Data

• Hazard Codes: Xi,N
• Statements: 36/37/38-50
• Safety Statements: 26-36-37/39-61
• RIDADR: 1759
• WGK Germany: 3
• RTECS: AJ4100000
• F: 8
• TSCA: Yes
• HazardClass: 9
• Hazardous Substances Data: 563-63-3(Hazardous Substances Data)

Usage

Chemical Description

Silver acetate is a chemical compound with the formula AgC2H3O2.

InChI:InChI=1/C2H4O2.Ag/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1

Synthetic route

acetic acid (64-19-7) + silver(l) oxide (20667-12-3) → silver(I) acetate (563-63-3)

Conditions	Yield
at 50℃; for 0.0833333h;	99%
In acetic acid react. of freshly prepared Ag2O (by electrolysis) with stoichiometric amounts of concd. acid, evapn. until begin of crystn., removal of remaining H2O under diminished pressure; apparatus described;;
In acetic acid crystn. on evapn. of the soln.;;
In acetic acid react. of freshly prepared Ag2O (by electrolysis) with stoichiometric amounts of concd. acid, evapn. until begin of crystn., removal of remaining H2O under diminished pressure; apparatus described;;

sodium acetate (127-09-3) + silver nitrate → silver(I) acetate (563-63-3)

Conditions	Yield
With acetic acid In water at 23℃;	91%
With acetic acid In water addn. of satd. aq. soln. of sodium acetate to satd. aq. soln. of AgNO3 contg. few drops of acetic acid in the dark; filtration, washing the residue with water, methanol, hexane, drying in vac.;	90%
In water soln. of AgNO3 in water was added to soln. of NaCH3CO2 in water; filtered in air, washed with water, EtOH, Et2O, dried in vacuo; elem. anal.;	64%

Pd[(μ-O2CMe)2Ag(HO2CMe)2]2 (1308661-15-5) + 1,10-phenanthroline hydrate (5144-89-8) → (1,10-phenanthroline)-palladium(II) acetate (35679-81-3) + silver(I) acetate (563-63-3)

Conditions	Yield
In benzene benzene soln. of ligand added with stirring to benzene soln. of Pd compd. (1:1 molar ratio), mixt. stirred at room temp. for 30 min; ppt. filtered off, concd., pptd. (heptane), dried, elem. anal.;	A 75% B n/a

Pd[(μ-O2CMe)2Ag(HO2CMe)2]2 (1308661-15-5) + tert-butyl alcohol (75-65-0) → palladium(II) pivalate + silver(I) acetate (563-63-3)

Conditions	Yield
In benzene benzene soln. of ligand added with stirring to benzene soln. of Pd compd. (3:1 molar ratio), mixt. stirred at room temp. for 1.5 h; ppt. filtered off, concd., crystd., dried, elem. anal.;	A 70% B n/a

2,4,6-trimethyl-[1,3,5]dioxathiane (53897-55-5) + moist silver oxide → silver(I) acetate (563-63-3) + silver formate + silver sulfide

Conditions	Yield
bei der Oxydation;

LACTIC ACID (849585-22-4) + water (7732-18-5) + Ag2O → carbon dioxide (124-38-9) + silver(I) acetate (563-63-3)

Conditions	Yield
at 100℃;

sodium formate (141-53-7) + acetic anhydride (108-24-7) → silver(I) acetate (563-63-3)

Conditions	Yield
In acetic anhydride boiling, pptn.;; recrystn. from glacial acetic acid;;

diammine silver(I) acetate → silver(I) acetate (563-63-3)

Conditions	Yield
With aldehyde In water
With aldehyde In water

diammine silver(I) acetate → ammonia (7664-41-7) + silver(I) acetate (563-63-3)

Conditions	Yield
In water in the air;
In water in the air;

silver perchlorate → silver(I) acetate (563-63-3)

Conditions	Yield
With trimethylamine acetate triacetatesolvate In not given addition of AgClO4 to a solution of the triacetatesolvate of trimethylamine acetate;;

Disilberdiazomethan + acetic acid (64-19-7) → acetic acid methyl ester (79-20-9) + silver(I) acetate (563-63-3)

Conditions	Yield
In acetic acid in the light within several days;;

Mn(C2H5N3O2)2(CH3COO)2*H2O + silver nitrate → silver(I) acetate (563-63-3)

Conditions	Yield
slow react.;

diammine silver(I) acetate → silver(I) acetate (563-63-3) + silver (7440-22-4)

Conditions	Yield
In water aq. soln. of Ag complex dried at 23°C for 24 h; detd. by X-ray diffraction;

potassium acetate (127-08-2) + silver nitrate → silver(I) acetate (563-63-3)

Conditions	Yield
In water at 20℃;	3.1 g

silver(I) acetate (563-63-3) + 2-<(N-cyclohexyl-N-methylamino)methyl>benzeneselenyl bromide (141819-09-2) → 2-(N-cyclohexyl,N-(methylamino)methyl)phenylselenyl acetate

Conditions	Yield
In dichloromethane for 2h;	100%

silver(I) acetate (563-63-3) + ethyl 3-bromo-2-oxo-1-azacyclodecane-10-carboxylate → (2R,9R)-9-Acetoxy-10-oxo-azecane-2-carboxylic acid ethyl ester

Conditions	Yield
In N,N-dimethyl-formamide at 100℃; for 3h;	100%

silver(I) acetate (563-63-3) + 4,6-bis(chloromethyl)-2,5-dimethoxytropone (114932-74-0) → 4-acetoxymethyl-6-chloromethyl-2,5-dimethoxytropone (114948-32-2)

Conditions	Yield
In acetic acid at 80℃; for 2h;	100%

1-chloro-1,3-dihydro-3,3-dimethyl-1,2-benziodoxole (69352-04-1) + silver(I) acetate (563-63-3) → 3,3-dimethyl-1λ3-benzo[d][1,2]iodoxol-1(3H)-yl acetate (175786-58-0)

Conditions	Yield
In acetonitrile at 20℃; for 15h;	100%
In acetonitrile Darkness;	98%
	97%

silver(I) acetate (563-63-3) + 11-{[(1R,3aS,5aR,5bR,7aR,9S,11aR,11bR,13aR,13bS)-9-Acetoxy-1-(1-bromomethyl-vinyl)-5a,5b,8,8,11a-pentamethyl-icosahydro-cyclopenta[a]chrysene-3a-carbonyl]-amino}-undecanoic acid methyl ester (173106-29-1) → 11-{[(1R,3aS,5aR,5bR,7aR,9S,11aR,11bR,13aR,13bS)-9-Acetoxy-1-(1-acetoxymethyl-vinyl)-5a,5b,8,8,11a-pentamethyl-icosahydro-cyclopenta[a]chrysene-3a-carbonyl]-amino}-undecanoic acid methyl ester (150841-09-1)

Conditions	Yield
With tetrabutylammomium bromide In toluene for 2h; Heating;	100%

silver(I) acetate (563-63-3) + 2-<(N-cyclohexyl-N-methylamino)methyl>benzeneselenyl bromide (141819-09-2) → 2-[(N-cyclohexyl-N-methylamino)methyl]benzeneselenyl acetate

Conditions	Yield
In dichloromethane	100%

silver(I) acetate (563-63-3) + 1-chloro-3,3-bis(trifluoromethyl)-1,3-dihydro-1λ3-benzo[d][1,2]iodaoxole (76215-48-0) → 3,3-bis(trifluoromethyl)-1λ3 -benzo[d][1,2]iodaoxol-1(3H)-yl acetate

Conditions	Yield
In acetonitrile Inert atmosphere; Darkness;	100%
In acetonitrile at 20℃; for 14.5h;	98%
In acetonitrile at 20℃; Darkness;	92%
In acetonitrile at 20℃; for 12h; Darkness;	90%

[{trans-Pt(NH3)2Cl}2-μ-spermidine-N1,N8]Cl3 + silver(I) acetate (563-63-3) → 3C2H4O2*C11H35N7O4Pt2

Conditions	Yield
In water at 40℃; for 24h;	100%

di-μ-chlorido-bis(η3-1,3-diphenylallyl)dipalladium(II) + silver(I) acetate (563-63-3) → {(π-PhCHCHCHPh)PdOAc}2

Conditions	Yield
In methanol; dichloromethane silver acetate added to soln. of Pd-compd. at room temp., stirred for 30 min.; filtered, evapd.;	100%

ammonium hexafluorophosphate + 6-([(1R)-endo]-(+)-bornyloxy)-2,2':6',2''-terpyridine + silver(I) acetate (563-63-3) → [Ag2(6-([(1R)-endo]-(+)-bornyloxy)-2,2':6',2''-terpyridine)2][PF6]2

Conditions	Yield
In methanol Sonication; mixt. was ultrasonicated for 10 min at room temp.; soln. was filtered and aq. NH4PF6 was added, pptn. was filtered off, washed with water, dried over P2O5; elem. anal.;	100%

ammonium hexafluorophosphate + 6-([(1S)-endo]-(-)-bornyloxy)-2,2':6',2''-terpyridine + silver(I) acetate (563-63-3) → [Ag2(6-([(1S)-endo]-(-)-bornyloxy)-2,2':6',2''-terpyridine)2][PF6]2

Conditions	Yield
In methanol Sonication; mixt. was ultrasonicated for 10 min at room temp.; soln. was filtered and aq. NH4PF6 was added, pptn. was filtered off, washed with water, dried over P2O5; elem. anal.;	100%

ammonium hexafluorophosphate + 6-([(1R)-endo]-(+)-bornyloxy)-6''-methyl-2,2':6',2''-terpyridine + silver(I) acetate (563-63-3) → [Ag2(6-([(1R)-endo]-(+)-bornyloxy)-6''-methyl-2,2':6',2''-terpyridine)2][PF6]2

Conditions	Yield
In methanol Sonication; mixt. was ultrasonicated for 10 min at room temp.; soln. was filtered and aq. NH4PF6 was added, pptn. was filtered off, washed with water, dried over P2O5; elem. anal.;	100%

[((C6H4N(2-adamantyl))2C)PdCl2]2 + water (7732-18-5) + silver(I) acetate (563-63-3) → [((C6H4N(2-adamantyl))2C)Pd(OH2)(OAc)2]

Conditions	Yield
In dichloromethane (N2); using of Schlenk techniques; combining of 1 equiv. of (((C6H4NC10H15)2C)PdCl2)2 with 4.1 equiv. of AgOAc in wet CH2Cl2; stirring under ambient conditions for 1.5 h; filtration, removal of volatiles in vac.;	100%

7,7-dichlorobicyclo<4.1.0>hept-3-ene (6802-78-4, 212268-85-4) + silver(I) acetate (563-63-3) → (1α,3β,4β,6α)-4-acetoxy-7,7-dibromobicyclo[4.1.0]heptan-3-ol

Conditions	Yield
Stage #1: 7,7-dichlorobicyclo<4.1.0>hept-3-ene; silver(I) acetate With iodine; acetic acid Inert atmosphere; Stage #2: With water at 20℃; for 48h; Inert atmosphere;	100%

tributylphosphine (998-40-3) + silver(I) acetate (563-63-3) → tris(tri-n-butyl phosphine)silver(I) acetate

Conditions	Yield
In diethyl ether (Ar), Ag acetate suspnd. in Et2O, reacted with 3 equiv. of (n-Bu)3P at 25°C for 1 h under stirring; evapd., elem. anal.;	100%

tributylphosphine (998-40-3) + silver(I) acetate (563-63-3) → tetra(tri-n-butyl phosphine)silver(I) acetate (1224594-74-4)

Conditions	Yield
In diethyl ether (Ar), Ag acetate suspnd. in Et2O, reacted with 4 equiv. of (n-Bu)3P at 25°C for 1 h under stirring; evapd., elem. anal.;	100%

silver(I) acetate (563-63-3) + Nevirapine (129618-40-2) → 11-cyclopropyl-4-methyl-6-oxo-6,11-dihydro-5H-dipyrido[3,2-b:2',3'-e][1,4]diazepin-2-yl acetate (1350539-29-5)

Conditions	Yield
With iodine In dichloromethane at 104℃; for 0.0833333h;	100%

1-(iodomethyl)-3-(2,2,2-trifluoroacetyl)-2,3-dihydro-1H-benzo[e]indole-7-carbonitrile (1363479-47-3) + silver(I) acetate (563-63-3) → (7-cyano-3-(2,2,2-trifluoroacetyl)-2,3-dihydro-1H-benzo[e]indol-1-yl)methyl acetate (1363479-50-8)

Conditions	Yield
In acetic acid for 48h; Reflux;	100%

5,10,15,20-tetratolyl-2-aza-21-diphenylphosphoryl-21-carbaporphyrin + silver(I) acetate (563-63-3) → C48H36AgN4

Conditions	Yield
In chloroform; acetonitrile	100%

5,10,15,20-tetratolyl-2-aza-3-diphenylophosphoryl-21-carbaporphyrin + silver(I) acetate (563-63-3) → silver(III) 5,10,15,20-tetratolyl-2-aza-3-diphenylphosphoryl-21-carbaporphiryn

Conditions	Yield
In dichloromethane; acetonitrile at 20℃; for 1h;	100%

C38H48Cl2N6NiO2Pd + silver(I) acetate (563-63-3) → C42H54N6NiO6Pd

Conditions	Yield
In dichloromethane at 20℃; for 0.333333h; Inert atmosphere; Optical yield = 54.545 %de;	100%

trans-1,2-dimethylcyclopentane (13012-46-9) + C40H76N2O2(2+)*2NO3(1-) + silver(I) acetate (563-63-3) + cobalt(II) acetate (71-48-7, 917-69-1, 5931-89-5, 55881-15-7, 68931-68-0, 68931-69-1, 93029-27-7) → C87H161CoN6O4(4+)*4NO3(1-)

Conditions	Yield
Stage #1: trans-1,2-dimethylcyclopentane; C40H76N2O2(2+)*2NO3(1-) In dichloromethane at 20℃; Stage #2: cobalt(II) acetate In dichloromethane at 20℃; for 12h; Stage #3: silver(I) acetate In dichloromethane for 12h;	100%

2,2-Dimethyl-1,3-diaminopropane (7328-91-8) + C40H76N2O2(2+)*2NO3(1-) + silver(I) acetate (563-63-3) + cobalt(II) acetate (71-48-7, 917-69-1, 5931-89-5, 55881-15-7, 68931-68-0, 68931-69-1, 93029-27-7) → C87H163CoN6O4(4+)*4NO3(1-)

Conditions	Yield
Stage #1: 2,2-Dimethyl-1,3-diaminopropane; C40H76N2O2(2+)*2NO3(1-) In dichloromethane at 20℃; Stage #2: cobalt(II) acetate In dichloromethane at 20℃; for 12h; Stage #3: silver(I) acetate In dichloromethane for 12h;	100%

C32H43BrP2Pd + silver(I) acetate (563-63-3) → C34H46O2P2Pd

Conditions	Yield
In toluene at 25℃; for 2h; Glovebox;	100%

trans-1,2-diaminocyclohexane monohydrochloride + {3-methyl-5-[{Bu3N+(CH2)3}2CMe]salicylaldehyde}(I-)2 + silver(I) acetate (563-63-3) + cobalt(II) acetate (71-48-7, 917-69-1, 5931-89-5, 55881-15-7, 68931-68-0, 68931-69-1, 93029-27-7) + silver nitrate → C56H95CoN4O5(2+)*2NO3(1-)

Conditions	Yield
Stage #1: trans-1,2-diaminocyclohexane monohydrochloride; {3-methyl-5-[{Bu3N+(CH2)3}2CMe]salicylaldehyde}(I-)2 With sodium t-butanolate In methanol for 4h; Inert atmosphere; Stage #2: silver nitrate In dichloromethane for 5h; Darkness; Stage #3: silver(I) acetate; cobalt(II) acetate Further stages;	100%

C22H20N(1+)*I(1-) + silver(I) acetate (563-63-3) → C22H20N(1+)*C2H3O2(1-)

Conditions	Yield
In methanol for 0.333333h;	100%

C22H20N(1+)*Br(1-) + silver(I) acetate (563-63-3) → C22H20N(1+)*C2H3O2(1-)

Conditions	Yield
In methanol for 0.333333h;	100%

tert-butylisonitrile (119072-55-8, 7188-38-7) + silver(I) acetate (563-63-3) → C5H9N*Ag(1+)*C2H3O2(1-)

Conditions	Yield
In dichloromethane at 20℃; for 1h; Inert atmosphere;	100%

sodium hexaflorophosphate + C48H46N4 + silver(I) acetate (563-63-3) → C48H46N4*Ag(1+)*F6P(1-)

Conditions	Yield
Stage #1: C48H46N4; silver(I) acetate In methanol Stage #2: sodium hexaflorophosphate	100%

8-amino quinoline (578-66-5) + silver(I) acetate (563-63-3) → N-(quinolin-8-yl)acetamide (33757-42-5)

Conditions	Yield
With nickel(II) triflate In chlorobenzene at 140℃; for 24h;	100%

Upstream product

• 64-19-7 acetic acid 
• 71-50-1 acetate 
• 7440-22-4 silver 
• 141-53-7 sodium formate 
• 20667-12-3 silver(l) oxide 
• 127-09-3 sodium acetate 
• 546-89-4 lithium acetate 
• 108-24-7 acetic anhydride 
• 127-08-2 potassium acetate 
• 1308661-15-5 Pd[(μ-O2CMe)2Ag(HO2CMe)2]2 
• 5144-89-8 1,10-phenanthroline hydrate 
• 75-65-0 tert-butyl alcohol 
• 917-70-4 lanthanum(III) acetate 
• 330660-35-0 silver cyanide 

Downstream Products

• 1604-29-1 1,1-dimethyl-2-propynyl acetate 
• 109698-45-5 (RS)-acetoxy(phenyl)methyl benzoate 
• 112-14-1 n-octyl acetate 
• 1454-85-9 1-Heptadecanol 
• 822-20-8 heptadecyl acetate 
• 10299-35-1 2,5-Diacetoxy-hexan 
• 102-76-1 triacetylglycerol 
• 119-61-9 benzophenone 
• 108-24-7 acetic anhydride 
• 93044-49-6 1-acetoxy-1-(4-acetoxy-3-methoxy-phenyl)-acetone 
• 18023-77-3 triacetoxy-cyclohexyl-silane 
• 62921-46-4 trans-2-acetoxy-1-cyclohexanol 
• 1759-71-3 trans-1,2-cyclohexanediol diacetate 
• 2396-76-1 cis-1,2-diacetoxycyclohexane 

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