1544-69-0Relevant academic research and scientific papers
The reaction of α,α,α-trifluoromethoxybenzene with AlCl3: A high yield preparation of α,α,α-trichloromethoxybenzene
Chen, Qiliang,Xu, Jie,Zhang, Wei
, p. 799 - 801 (2002)
α,α,α-Trifluoromethoxybenzene was allowed to react with AlCl3 in CH2Cl2 to afford α,α,α-trichloromethoxybenzene in excellent yield and purity.
Selective aliphatic fluorination by halogen exchange in mild conditions
Saint-Jalmes, Laurent
, p. 85 - 90 (2007/10/03)
HF-Base media, in particular (HF)10-pyridine or (HF) 3-triethylamine, allow aliphatic chlorine-fluorine exchanges on acid-sensitive molecules. Depending on the nature (pyridine or triethylamine), stoichiometry of the base and temperature, selective mono-, di-, or tri-chlorine-fluorine exchanges on trichloromethyl groups alpha to sulfur, oxygen and carbon atoms can be obtained.
