154405-97-7

Upstream product

• 60612-87-5 ethyl 3-chlorobenzimidate hydrochloride 
• 587-04-2 m-Chlorobenzaldehyde 
• 34158-71-9 3-chlorobenzaldehyde oxime 
• 766-84-7 3-chloro-benzonitrile 
• 109345-74-6 4-Carbomethoxy-5-methoxy-2-(3'-chlorophenyl)oxazole 

Downstream Products

• 1370731-55-7 methyl 2-(m-chlorophenyl)-5-phenyloxazole-4-carboxylate 
• 1370731-56-8 C₂₂H₁₄Cl₂N₂O₆ 
• 925940-96-1 2-(3-chlorophenyl)-1,3-oxazole-4-carboxylic acid 

Relevant academic research and scientific papers

Rhodium-catalyzed heterocycloaddition route to 1,3-oxazoles as building blocks in natural products synthesis

Rhodium(II) acetate serves as a catalyst for the heterocycloaddition reaction of diazodicarbonyl compounds with nitriles to give functionalized 1,3-oxazole derivatives in a simple one-step procedure. In particular, dimethyl diazomalonate undergoes this re

Pd(ii)-catalyzed direct C5-arylation of azole-4-carboxylates through double C-H bond cleavage

The first palladium-catalyzed direct C5-arylation of azole-4-carboxylates with simple unactivated arenes through double C-H bond cleavage is realized. This protocol provided a straightforward access to diverse 5-arylsubstituted azole-4-carboxylic derivatives with good functional group tolerance. The Royal Society of Chemistry 2012.