Rhodium-catalyzed heterocycloaddition route to 1,3-oxazoles as building blocks in natural products synthesis

DOI: 10.1016/S0040-4020(01)87261-6

Source and publish data:

Tetrahedron p. 5445 - 5459 (1993)

Update date:2022-08-04

Topics:

Authors:

Connell Connell

Tebbe Tebbe

Gangloff

Helquist

Akermark

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)87261-6

Rhodium(II) acetate serves as a catalyst for the heterocycloaddition reaction of diazodicarbonyl compounds with nitriles to give functionalized 1,3-oxazole derivatives in a simple one-step procedure. In particular, dimethyl diazomalonate undergoes this re

Full text of DOI:10.1016/S0040-4020(01)87261-6

Products guided by the article

Product name:4-Oxazolecarboxylic acid, 2-(3-chlorophenyl)-, methyl ester

Cas No:154405-97-7

R&D Labs maybe for 154405-97-7

GenicBio Limited

Contact:+86-(0)21-3770 9035

Address:Room 301, Building 2, Meijiabang Road 1508, Shanghai China
Nanjing Chemical Material Corp.(NCMC)

website:http://www.njchemm.com

Contact:0086-25-83172879

Address:B12 Technology and Innovation Building, Nanjing Tech University, No.5 New Model Road
Chongqing KonAo Health Co.,Ltd

Contact:13687578375

Address:wuhan hubei china
Hefei TNJ chemical industry co.,ltd

website:https://www.tnjchem.com

Contact:+86-551-65418695

Address:B911 Xincheng Business Center, Qianshan Road, Hefei Anhui China
Hangzhou Hysen Pharma co.,Ltd.

website:http://www.hysenpharma.cn/

Contact:0086-571-88298791

Address:#701,Gudun Road Hangzhou

Relevant to this article

Stereochemistry of the methoxide induced rearrangement of an α-bromophosphonamidate: Cleavage of the P-N and P-C bonds in the azaphosphiridine oxide intermediate

Doi:10.1039/a604093d
(1997)
Cluster chemistry. XC. Some complexes obtained from reactions between M3(CO)12 (M = Ru or Os) or Ru3(μ-dppm)(CO)10 and 2-substituted triphenylphosphines and related keto-phosphine ligands

Doi:10.1016/0022-328X(94)80013-8
(1994)
17β-Hydroxywithanolides as Sensitizers of Renal Carcinoma Cells to Tumor Necrosis Factor-α Related Apoptosis Inducing Ligand (TRAIL) Mediated Apoptosis: Structure-Activity Relationships

Doi:10.1021/acs.jmedchem.7b00069
(2017)
Synthesis of cyclophanes with intra-annular functionality and cage structure

Doi:10.1021/jo950957y
(1996)
Synthesis and biological evaluation of santacruzamate A and analogs as potential anticancer agents

Doi:10.1039/c4ra13889a
(2015)
Reactions of the σ,π-furyl complex [Fe₂(CO) ₆(μ-Fu)(μ-PFu₂)] (Fu = C₄H₃O) with phosphines: Carbonyl substitution, migratory carbonyl insertion and cyclometallation-induced furan elimination

Doi:10.1016/j.jorganchem.2013.05.026
(2014)

Article Doi