Rhodium-catalyzed heterocycloaddition route to 1,3-oxazoles as building blocks in natural products synthesis

DOI: 10.1016/S0040-4020(01)87261-6

Source and publish data:

Tetrahedron p. 5445 - 5459 (1993)

Update date:2022-08-04

Topics:

Authors:

Connell Connell

Tebbe Tebbe

Gangloff

Helquist

Akermark

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Article abstract of DOI:10.1016/S0040-4020(01)87261-6

Rhodium(II) acetate serves as a catalyst for the heterocycloaddition reaction of diazodicarbonyl compounds with nitriles to give functionalized 1,3-oxazole derivatives in a simple one-step procedure. In particular, dimethyl diazomalonate undergoes this re

Full text of DOI:10.1016/S0040-4020(01)87261-6

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Product name:4-Oxazolecarboxylic acid, 2-(3-chlorophenyl)-, methyl ester

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