154661-03-7Relevant academic research and scientific papers
PHOSPHATRIAFULVENES - PHOSPHAALKENES WITH INVERSE ELECTRON DENSITY
Fuchs, Eberhard P. O.,Heydt, Heinrich,Regitz, Manfred,Schoeller, Wolfgang W.,Busch, Thilo
, p. 5111 - 5114 (1989)
The phosphatriafulvenes 3a,b, accessible from the cyclopropenone 1 and the lithium phosphides 2, possess inverse electron density as indicated by structure B; this can also be deduced from ab initio calculations.In accord with the electronic structure, me
Organophosphorus compounds - 60. Reactions of phosphatriafulvenes with nucleophilic partners
Fuchs,Krebs,Heydt,Regitz
, p. 759 - 774 (2007/10/02)
The phosphatriafulvenes 1a,b - phosphaalkenes with inverse electron density - react primarily at the three-membered ring with nucleophilic reagents. From their reactions with organolithium compounds 2a-c and Grignard reagents 5a,b the cyclopropenylphosphi
