154706-34-0

Basic information

• Product Name: Acetic acid (2S,4aR,6R,7R,8R,8aR)-6-((R)-1-acetoxy-2,2-bis-phenylsulfanyl-ethyl)-8-azido-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester
• Synonyms: Acetic acid (2S,4aR,6R,7R,8R,8aR)-6-((R)-1-acetoxy-2,2-bis-phenylsulfanyl-ethyl)-8-azido-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester
• CAS NO: 154706-34-0
• Molecular Weight: 621.735
• Mol File: 154706-34-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Acetic acid (2S,4aR,6R,7R,8R,8aR)-6-((R)-1-acetoxy-2,2-bis-phenylsulfanyl-ethyl)-8-azido-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid (2S,4aR,6R,7R,8R,8aR)-6-((R)-1-acetoxy-2,2-bis-phenylsulfanyl-ethyl)-8-azido-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester(154706-34-0)
• EPA Substance Registry System: Acetic acid (2S,4aR,6R,7R,8R,8aR)-6-((R)-1-acetoxy-2,2-bis-phenylsulfanyl-ethyl)-8-azido-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester(154706-34-0)

Safety Data

• Hazardous Substances Data: 154706-34-0(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 52443-07-9 3,4,5,7-tetra-O-acetyl-2,6-anhydro-D-glycero-L-manno-heptonitrile 
• 154706-31-7 Trifluoro-methanesulfonic acid (2S,4aR,6R,7S,8R,8aS)-6-(2,2-bis-phenylsulfanyl-acetyl)-7-hydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester 
• 154706-32-8 Trifluoro-methanesulfonic acid (2S,4aR,6R,7S,8R,8aS)-7-hydroxy-6-((R)-1-hydroxy-2,2-bis-phenylsulfanyl-ethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester 
• 154706-30-6 1-((2S,4aR,6R,7R,8R,8aR)-7,8-Dihydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-2,2-bis-phenylsulfanyl-ethanone 
• 139302-05-9 (2S,4aR,6S,7R,8R,8aR)-7,8-Dihydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-6-carbonitrile 
• 13307-76-1 [bis(phenylthio)methyl]lithium 
• 3737-59-5 2,6-anhydro-D-glycero-L-manno-heptononitrile 
• 154706-33-9 Acetic acid (2S,4aR,6R,7S,8S,8aS)-6-((R)-1-acetoxy-2,2-bis-phenylsulfanyl-ethyl)-2-phenyl-8-trifluoromethanesulfonyloxy-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 

Downstream Products

• 154706-35-1 (2S,4aR,5aS,6R,7R,8aR,9R,9aR)-9-Azido-2-phenyl-7-phenylsulfanyl-octahydro-furo[2',3':5,6]pyrano[3,2-d][1,3]dioxin-6-ol 
• 154706-36-2 2,2-Dimethyl-propionic acid (2S,4aR,5aR,6R,7R,8aR,9R,9aR)-9-azido-2-phenyl-7-phenylsulfanyl-octahydro-furo[2',3':5,6]pyrano[3,2-d][1,3]dioxin-6-yl ester 
• 154706-38-4 2,2-Dimethyl-propionic acid (2S,4aR,5aR,6R,7R,8aR,9S,9aR)-7-(4-acetylamino-2-oxo-2H-pyrimidin-1-yl)-9-amino-2-phenyl-octahydro-furo[2',3':5,6]pyrano[3,2-d][1,3]dioxin-6-yl ester 
• 154706-37-3 2,2-Dimethyl-propionic acid (2S,4aR,5aR,6R,7R,8aR,9S,9aR)-7-(4-acetylamino-2-oxo-2H-pyrimidin-1-yl)-9-azido-2-phenyl-octahydro-furo[2',3':5,6]pyrano[3,2-d][1,3]dioxin-6-yl ester 
• 154706-39-5 2,2-Dimethyl-propionic acid (2S,4aR,5aR,6R,7R,8aR,9S,9aR)-7-(4-acetylamino-2-oxo-2H-pyrimidin-1-yl)-2-phenyl-9-[3-(2,2,2-trichloro-acetyl)-ureido]-octahydro-furo[2',3':5,6]pyrano[3,2-d][1,3]dioxin-6-yl ester 
• 1053640-25-7 (2S,4aR,6R,7R,8S,8aR)-8-Azido-6-((R)-1-hydroxy-2,2-bis-phenylsulfanyl-ethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol 

Relevant articles and documents

Synthesis of the ezomycin octosyl nucleoside

Efficient chain extension of β-D-galactopyranosyl cyanide, cyclization to a bicyclic octose, and then attachment of cytosine affords the ezomycinoctosyl nucleoside 17 in a form suitable for elaboration to the ezomycins (e.g., 1).