15485-32-2

Basic information

• Product Name: p-Toluidine, N-(p-chlorobenzylidene)- (6CI,7CI,8CI)
• Synonyms: p-Toluidine, N-(p-chlorobenzylidene)- (6CI,7CI,8CI);p-Toluidine,N-(p-chlorobenzylidene)-;N-(4-Chlorobenzylidene)-4-methylaniline;N-(p-Chlorobenzylidene)-p-toluidine;p-Chlorobenzal-p-toluidine;N-(4-CHLOROBENZYLIDENE)-P-TOLUIDINE
• CAS NO: 15485-32-2
• Molecular Formula: C₁₄H₁₂ClN
• Molecular Weight: 229.70478
• Mol File: 15485-32-2.mol
• Article Data: 40

Chemical Properties

• Melting Point: 144℃
• Appearance: /
• CAS DataBase Reference: p-Toluidine, N-(p-chlorobenzylidene)- (6CI,7CI,8CI)(CAS DataBase Reference)
• NIST Chemistry Reference: p-Toluidine, N-(p-chlorobenzylidene)- (6CI,7CI,8CI)(15485-32-2)
• EPA Substance Registry System: p-Toluidine, N-(p-chlorobenzylidene)- (6CI,7CI,8CI)(15485-32-2)

Safety Data

• Hazardous Substances Data: 15485-32-2(Hazardous Substances Data)

Upstream product

• 104-88-1 4-chlorobenzaldehyde 
• 106-49-0 p-toluidine 
• 33863-79-5 N-(4-chlorobenzyl)-4-methylbenzeneamine 
• 873-76-7 para-Chlorobenzyl alcohol 
• 99-99-0 1-methyl-4-nitrobenzene 
• 104-86-9 4-chlorobenzylamine 

Downstream Products

• 1145685-67-1 diethyl {(4-chlorophenyl)[(4-tolyl)amino]methyl}phosphonate 
• 903734-72-5 5-(4-chlorophenyl)-1-(p-tolyl)-3-(p-tolylamino)-1H-pyrrol-2(5H)-one 
• 33863-79-5 N-(4-chlorobenzyl)-4-methylbenzeneamine 
• 5405-15-2 N-benzyl-N-(4-methylphenyl)amine 

Relevant articles and documents

Molecular Conformation and Electronic Structure. VII. The Structure of the Isomorphic System p-Chloro-N-(p-methylbenzylidene)aniline and p-Methyl-N-(p-chlorobenzylidine)aniline

The isomorphous crystal structures of two hetero para disubstituted derivatives of benzylideneaniline, BA, have been determined.Both p-chloro-N-(p-methylbenzylidene)aniline, MeCl, and p-methyl-N-(p-chlorobenzylidene)aniline, ClMe, (C14H12ClN, Mr/sub

Synthesis and characterization of tetrachloro-1,3-oxazepine derivatives and evaluation of their biological activities

6,7,8,9-Tetrachloro[1,3]oxazepine-1,5-dione derivatives 1b-10b have been synthesized by reacting Schiff bases 1a-10a with tetrachlorophthalic anhydride (TCPA) under (2 + 5 → 7) cycloaddition reaction conditons. All reactions had been monitored using TLC.

Visible light photocatalytic aerobic oxidative synthesis of imines from alcohols and amines on dye-sensitized TiO2

A general visible light photocatalytic protocol for the synthesis of imines via a two-step one-pot route on alizarin red S (ARS)-sensitized TiO2 was uncovered. This efficient synthesis protocol involves one step of the highly selective formation of aldehydes from the oxidation of alcohols with O2 on ARS-sensitized TiO2 photocatalyst, and a subsequent step of condensation of newly formed aldehydes with various amines on TiO2 to afford imines in one pot. Anatase TiO2 provides a versatile platform for catalytic amounts of ARS (0.67 mol%) to facilitate the electron transfer from dye traversing its conduction band to O2 under green LED irradiation. Moreover, the Lewis acid sites of TiO2 can promote the formation of imines from aldehydes and amines in very high isolated yields. We took advantage of both the photocatalytic and catalytic properties of TiO2 to significantly expand the scope of imines. Our work suggests that the synthetic applications of TiO2 photocatalysis can be achievable under mild conditions by exploring the excellent functionalities of TiO2.