154859-08-2

Downstream Products

• 154859-10-6 <2'R,2''R,6'R,6''R> methyl 6-O-(tert-butyldiphenylsilyl)-2-O,3-O-(6',6''-diphenyloctahydro-2',2''-bipyran-2',2''-diyl)-α-D-glucopyranoside 
• 303988-73-0 (2R,6R,7R,9R,14R,15R)-dimethyl 2,9-diphenyl-1,8,13,16-tetraoxadispiro-[5.0.5.4]hexadecane-14,15-dicarboxylate 
• 154859-12-8 <2'R,2''R,6'R,6''R> methyl 4-O-benzoyl-6-O-(tert-butyldiphenylsilyl)-2-O,3-O-(6',6''-diphenyloctahydro-2',2''-bipyran-2',2''-diyl)-α-D-glucopyranoside 
• 154859-14-0 <2'R,2''R,6'R,6''R> methyl 4-O-acetyl-6-O-(tert-butyldiphenylsilyl)-2-O,3-O-(6',6''-diphenyloctahydro-2',2''-bipyran-2',2''-diyl)-α-D-glucopyranoside 
• 160413-04-7 (2'S,2''S,6'S,6''S) 1-O,6-O-(6,6'-diphenyl-3,3',4,4',5,5',6,6'-octahydro-2,2'-bi-2H-pyran-2,2'-diyl)-2-O,3-O,4-O,5-O-tetrabenzyl-D-myo-inositol 
• 160413-02-5 (2'S,2''S,6'S,6''S) 2-O,5-O-dibenzoyl-1-O,6-O-(6,6'-diphenyl-3,3',4,4',5,5',6,6'-octahydro-2,2'-bi-2H-pyran-2,2'-diyl)-D-myo-inositol 
• 154859-09-3 (6S,6'S)-6,6'-Diphenyl-5,6,5',6'-tetrahydro-4H,4'H-[2,2']bipyranyl 
• 303988-74-1 (2R,6R,7R,9R)-dimethyl 2,9-diphenyl-1,8,13,16-tetraoxadispiro-[5.0.5.4]hexadec-14-ene-14,15-dicarboxylate 
• 303988-75-2 (2R,6R,7R,9R)-2,9-diphenyl-1,8,13,16-tetraoxadispiro-[5.0.5.4]hexadec-14-ene-14,15-dinitrile 
• 236115-63-2 C₂₈H₃₂N₆O₅ 
• 112607-34-8 (6S) 6-phenyltetrahydro-2H-pyran-2-one 
• 156599-71-2 (2R,6S,7R,9R,14S)-14-tert-Butyl-2,9-diphenyl-1,8,13,16-tetraoxa-dispiro[5.0.5.4]hexadecane 

Relevant academic research and scientific papers

Dispiroketals in Synthesis (Part 19): Dispiroketals as Enantioselective and Regioselective Protective Agents for Symmetric Cyclic and Acyclic Polyols.

The enantioselective preparation of both enantiomers of a C2-symmetric diphenyl-bidihydropyran 3 and 4 is described.The application of enantiopure bi-dihydropyrans 1-4 towards the simultaneous enantioselective differentiation and regioselective protection of a range of cyclic and acyclic symmetrical polyols (23, 37, 43, 45, 54, 61 and 66) is investigated.Several deprotections utilising trifluoroacetic acid (TFA) and a transketalisation with acidic glycerol are presented.