154920-05-5

Basic information

• Product Name: (2R,3R)-2-methyl-1-phenyl-hex-5-en-3-ol
• Synonyms: (2R,3R)-2-methyl-1-phenyl-hex-5-en-3-ol
• CAS NO: 154920-05-5
• Molecular Weight: 190.285
• Mol File: 154920-05-5.mol

Chemical Properties

• CAS DataBase Reference: (2R,3R)-2-methyl-1-phenyl-hex-5-en-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3R)-2-methyl-1-phenyl-hex-5-en-3-ol(154920-05-5)
• EPA Substance Registry System: (2R,3R)-2-methyl-1-phenyl-hex-5-en-3-ol(154920-05-5)

Safety Data

• Hazardous Substances Data: 154920-05-5(Hazardous Substances Data)

Upstream product

• 5445-77-2 (2R)-2-methyl-3-phenylpropanal 
• 547713-49-5 (3aS,7aS)-1,3-bis[(4-bromophenyl)methyl]-2-chlorooctahydro-2-(2-propenyl)-1H-1,3,2-benzodiazasilole 
• 154920-03-3 (1R,2R)-1-Hydroxy-2-methyl-1-phenyl-hex-5-en-3-one 
• 159345-06-9 (2R)-N-[(1S,2S)-2-hydroxy-1-methyl-2-phenylethyl]-N,2-dimethyl-3-phenylpropionamide 
• 100-39-0 benzyl bromide 
• 1730-25-2 allylmagnesium bromide 
• 154920-04-4 (4R,5S,6R)-4-Allyl-2,2,5-trimethyl-6-phenyl-[1,3]dioxane 

Downstream Products

• 1094537-97-9 ((2R,3R)-3-benzyloxy-2-methylhex-5-enyl)benzene 
• 192574-01-9 (1R,2S,7R,8R)-2-Benzyloxy-1-[(S)-2-((1S,2R)-3-benzyloxy-1-benzyloxymethyl-1,2-dihydroxy-propyl)-oxiranyl]-7-(tert-butyl-dimethyl-silanyloxy)-1-hydroxy-8-methyl-9-phenyl-nonan-3-one 
• 192574-00-8 (2R,3S,5S,6S,11R,12R)-1,6-Bis-benzyloxy-3-benzyloxymethyl-11-(tert-butyl-dimethyl-silanyloxy)-2,3,5-trihydroxy-12-methyl-4-methylene-13-phenyl-tridecan-7-one 
• 192573-95-8 (1S,3R,4S,5R,6R,7S)-7-Benzyloxy-3,4-bis-benzyloxymethyl-1-[(4R,5R)-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-6-phenyl-hexyl]-5-hydroxymethyl-2,8-dioxa-bicyclo[3.2.1]octane-4,6-diol 
• 192573-98-1 (1R,4R,5R,6S)-6-Benzyloxy-4-((E)-3-benzyloxy-1-benzyloxymethyl-propenyl)-1-[(4R,5R)-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-6-phenyl-hexyl]-2,7-dioxa-bicyclo[2.2.1]heptan-5-ol 
• 192573-93-6 [(R)-4-Benzenesulfonyl-1-((R)-1-methyl-2-phenyl-ethyl)-butoxy]-tert-butyl-dimethyl-silane 
• 192573-92-5 (2R,3R)-6-Benzenesulfonyl-2-methyl-1-phenyl-hexan-3-ol 
• 146389-62-0 (+)-zaragozic acid 
• 171190-05-9 tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,6(4E,6R),7R]-1-(4-acetoxy-5-methyl-6-phenylhexyl)-7-(tert-butoxycarbonyloxy)-4-hydroxy-6-(6-methyl-9-phenyl-4-nonenoyl)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate 
• 171190-04-8 tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-1-(4-acetoxy-5-methyl-6-phenylhexyl)-7-(tert-butoxycarbonyl)oxy-4,6-dihydroxy-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate 
• 156661-55-1 (1S,3S,4S,5R,6R,7R,4'R,5'R)-1-[4'-acetoxy-5'-methyl-6'-phenylhex-1'-yl]-3,4,5-tris(2,2-dimethylpropionyl)-4,6,7-trihydroxy-2,8-dioxabicyclo[3.2.1]octane 
• 164215-53-6 tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-6,7-diacetoxy-1-(4-acetoxy-5-methyl-6-phenylhexyl)-4-hydroxy-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate 
• 191935-36-1 tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-4,6,7-trihydroxy-1-(4-hydroxy-5-methyl-6-phenylhexyl)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate 
• 191935-35-0 tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-1-(4-benzyloxy-5-methyl-6-phenylhexyl)-4,6,7-trihydroxy-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate 

Relevant articles and documents

Studies towards the synthesis of the zaragozic acids: Synthesis of the bicyclic acetal core of zaragozic acid C.

The bicyclic core 6 of zaragozic acid C (7) was prepared by the epoxide cyclisation reaction 21 → 22 → 15. Acetal 15 was also obtained by acid-promoted rearrangement of the isomeric acetal 19.

The asymmetric syntheses of the C-1 sidechains of zaragozic acid A and zaragozic acid C

The asymmetric syntheses of the C-1 sidechains of zaragozic acid A and C are described. Aldol reaction defines the chirality at C-4' and C-5' in two independent routes. Multigram preparation as well as a route amenable to derivatization are highlights of