154928-15-1

Basic information

• Product Name: 1-Methyl-[2,2'-bipyridin]-6(1H)-one
• Synonyms: 1-methyl-2,2'-bipyridine-6-one
• CAS NO: 154928-15-1
• Molecular Formula: C₁₁H₁₀N₂O
• Molecular Weight: 186.2099
• Mol File: 154928-15-1.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 415.6±38.0 °C(Predicted)
• Appearance: /
• Density: 1.193±0.06 g/cm3(Predicted)
• PKA: 5.75±0.19(Predicted)
• CAS DataBase Reference: 1-Methyl-[2,2'-bipyridin]-6(1H)-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Methyl-[2,2'-bipyridin]-6(1H)-one(154928-15-1)
• EPA Substance Registry System: 1-Methyl-[2,2'-bipyridin]-6(1H)-one(154928-15-1)

Safety Data

• Hazardous Substances Data: 154928-15-1(Hazardous Substances Data)

Usage

General Description

1-Methyl-[2,2'-bipyridin]-6(1H)-one, also known as 5-methyl-2,2'-bipyridine-6(1H)-one, is a chemical compound with the molecular formula C12H10N2O. It belongs to the family of bipyridine compounds and is commonly used as a ligand in coordination chemistry. This chemical is frequently employed in the synthesis of metal complexes and as a building block for the preparation of various organic compounds. It is also used in research and development for its unique chemical and structural properties. Additionally, 1-Methyl-[2,2'-bipyridin]-6(1H)-one has potential applications in fields such as pharmaceuticals, material science, and catalysis due to its versatile and diverse properties.

Upstream product

• 366-18-7 [2,2]bipyridinyl 
• 74-88-4 methyl iodide 
• 77972-47-5 1-methyl-2-(2′-pyridyl)pyridinium iodide 

Downstream Products

• 152194-39-3 6-(diphenylphosphino)-2,2'-bipyridine 
• 10495-73-5 2-bromo-6-(pyridin-2-yl)pyridine 
• 13040-77-2 6-Chloro-[2,2']bipyridinyl 

Relevant articles and documents

Synthesis and structures of two mononuclear iron(ii) complexes derived from polypyridine ligands

Three polypyridine ligands such as tri(2-pyridyl)methane, (2,2’-bipyridin-6-yl)di(2-pyridyl)methane and 2,6-bis[di(2-pyridyl)methyl] pyridine as well as their new iron(II) mononuclear complexes have been obtained in a one-pot synthesis. Detailed structural analyses and magnetic susceptibility measurements confirm the expected six-coordinate octahedral geometry and the metric parameters are consistent with lowspin iron(II) in the complexes.

Synthesis of new pyrrole-pyridine-based ligands using an in situ Suzuki coupling method

The compounds 6-(pyrrol-2-yl)-2,2'-bipyridine, 2-(pyrrol-2-yl)-1,10- phenanthroline and 2-(2-(N-methylbenz[d,e]imidazole)-6- (pyrrol-2-yl)-pyridine were synthesized by using an in situ generated boronic acid for the Suzuki coupling. Crystals of the products could be grown and exhibited interesting structures by X-ray analysis, one of them showing a chain-like network with the adjacent molecules linked to each other via intermolecular N-H...N hydrogen bonds.

Synthesis and molecular structure of the potentially binucleating tridentate ligand 6-diphenylphosphino-2,2'-bipyridyl

An improved procedure for the synthesis of 6-chloro-2,2'-bipyridyl from 2,2'-bipyridine is described.Treatment of this compound with LiPPh2 leads to the formation of the new, potentially binucleating tridentate ligand, 6-diphenylphosphino-2,2'-bipyridyl.The spectroscopic properties of this ligand and its molecular structure, as established by X-ray crystallography, are described.