1551161-32-0

Basic information

• Product Name: Ru(tetratolylporphyrin)(CO)(2-(pyrid-2-yl)pyrazine)
• Synonyms: Ru(tetratolylporphyrin)(CO)(2-(pyrid-2-yl)pyrazine)
• CAS NO: 1551161-32-0
• Molecular Weight: 955.096
• Mol File: 1551161-32-0.mol

Chemical Properties

• CAS DataBase Reference: Ru(tetratolylporphyrin)(CO)(2-(pyrid-2-yl)pyrazine)(CAS DataBase Reference)
• NIST Chemistry Reference: Ru(tetratolylporphyrin)(CO)(2-(pyrid-2-yl)pyrazine)(1551161-32-0)
• EPA Substance Registry System: Ru(tetratolylporphyrin)(CO)(2-(pyrid-2-yl)pyrazine)(1551161-32-0)

Safety Data

• Hazardous Substances Data: 1551161-32-0(Hazardous Substances Data)

Upstream product

• 60860-94-8 (ethanol)(carbonyl)(5,10,15,20-tetra-p-tolylporphyrinato-κ4N)ruthenium(II) 
• 93844-96-3 2-(pyridin-2-yl)pyrazine 

Downstream Products

• 1551161-48-8 Ru(tetratolylporphyrin)(CO)(2-(pyrid-2-yl)pyrazine)Pd(Me)Cl 
• 1551161-48-8 Ru(tetratolylporphyrin)(CO)(2-(pyrid-2-yl)pyrazine)Pd(Me)Cl 

Relevant articles and documents

Synthesis of trinuclear Pd-Ru-Pd porphyrin complexes with axially ligated Pd centers. Prominent metal-to-ligand charge transfer band in the visible region

Ru-porphyrin complexes with pyridylpyrazine as metal coordination sites were synthesized. Introduction of Pd-alkyl units to the binding site led to the formation of a novel Pd-Ru-Pd trinuclear complex. The metalation causes drastic changes in the electrochemical and photophysical properties. The trinuclear complex exhibited a prominent metal-to-axial ligand charge transfer band in the visible region due to small energy gap between the Ru-based HOMO and the axial ligand-based LUMO. These changes resulted in the drastic color change from orange to green.